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dc.contributor.authorD'Alessio, D-
dc.contributor.authorSobolev, AN-
dc.contributor.authorSkelton, BW-
dc.contributor.authorFuller, RO-
dc.contributor.authorWoodward, RC-
dc.contributor.authorLengkeek, NA-
dc.contributor.authorFraser, BH-
dc.contributor.authorMassi, M-
dc.contributor.authorOgden, MI-
dc.identifier.citationD’Alessio, D., Sobolev, A. N., Skelton, B. W., Fuller, R. O., Woodward, R. C., Lengkeek, N. A., Fraser, B. H. Massi., M, & Ogden, M. I. (2014). Lanthanoid “bottlebrush” clusters: remarkably elongated metal–oxo core structures with controllable lengths. Journal of the American Chemical Society, 136(43), 15122-15125. doi:10.1021/ja506677hen_AU
dc.descriptionACS AuthorChoice - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. Terms of use can be found here:
dc.description.abstractLarge metal–oxo clusters consistently assume spherical or regular polyhedral morphologies rather than high-aspect-ratio structures. Access to elongated core structures has now been achieved by the reaction of lanthanoid salts with a tetrazole-functionalized calixarene in the presence of a simple carboxylate co-ligand. The resulting Ln19 and Ln12 clusters are constructed from apex-fused Ln5O6 trigonal bipyramids and are formed consistently under a range of reaction conditions and reagent ratios. Altering the carboxylate co-ligand structure reliably controls the cluster length, giving access to a new class of rod-like clusters of variable length. © 2014 American Chemical Societyen_AU
dc.publisherJournal of the American Chemical Societyen_AU
dc.subjectRare earthsen_AU
dc.titleLanthanoid “bottlebrush” clusters: remarkably elongated metal–oxo core structures with controllable lengthsen_AU
dc.typeJournal Articleen_AU
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