Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/7723
Title: Characterization of the seposition of n-Octanohydroxamate on copper surfaces
Authors: Parker, GK
Holt, SA
Keywords: Copper
Electrodes
X-ray sources
Electrolytes
Raman spectroscopy
Neutron reflectors
Issue Date: Oct-2012
Publisher: ECS
Citation: Parker, G. K., & Holt, S. A. (2014). Characterization of the deposition of n-Octanohydroxamate on copper surfaces. Journal of the Electrochemical Society, 161(5), D277-D286 doi:10.1149/2.070405jes
Abstract: The interaction of n-octanohydroxamate with a copper electrode was investigated using cyclic voltammetry, contact angles, surface-enhanced Raman scattering, neutron reflectometry and X-ray reflectometry. The data demonstrated that hydroxamate specifically adsorbed at underpotentials in the keto tautomeric form, but the layer was hydrophilic and contained >50% water. In the CuI stability region the hydroxamate moiety took on the enol tautomeric form but the interface remained hydrated. Co-adsorption of electrolyte species was observed at underpotentials. The adsorbed hydroxamate at the surface did not prevent the formation of oxide in the CuI stability region. A hydrophobic non-passivating multilayer of copper n-octanohydroximate formed in the CuII stability region. © 2014, The Electrochemical Society.
Gov't Doc #: 7285
URI: http://dx.doi.org/10.1149/2.070405jes
http://apo.ansto.gov.au/dspace/handle/10238/7723
ISSN: 0013-4651
Appears in Collections:Journal Articles

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.