Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/7700
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dc.contributor.authorOmoto, K-
dc.contributor.authorYashima, M-
dc.contributor.authorHester, JR-
dc.date.accessioned2016-10-11T00:06:29Z-
dc.date.available2016-10-11T00:06:29Z-
dc.date.issued2013-12-11-
dc.identifier.citationOmoto, K., Yashima, M., & Hester, J. R. (2014). Structural Origin of the Anisotropic Thermal Expansion of a K2NiF4-type Oxide CaErAlO4 through Interatomic Distances. Chemistry Letters, 43(4), 515-517 doi: http://doi.org/10.1246/cl.131164en_AU
dc.identifier.govdoc7262-
dc.identifier.urihttp://doi.org/10.1246/cl.131164en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/7700-
dc.description.abstractThe anisotropic thermal expansion and crystal structure of K2NiF4-type CaErAlO4 have been investigated by neutron diffraction from 298 to 1473 K. The average thermal expansion coefficient (TEC) along the c axis αc is larger than that along the a axis, mainly due to the larger Al–(apical oxygen O2) TEC compared to the Al–(equatorial O1) TEC. The larger Al–O2 TEC is attributable to the weaker Al–O2 bond. Contrary to the literature, the mean TEC of K2NiF4-type CaErAlO4 is larger than that of perovskite-type ErAlO3.en_AU
dc.language.isoenen_AU
dc.publisherChemistry Lettersen_AU
dc.subjectANISOTROPYen_AU
dc.subjectTHERMAL EXPANSIONen_AU
dc.subjectNEUTRON DIFFRACTIONen_AU
dc.subjectMOLECULAR STRUCTUREen_AU
dc.subjectPEROVSKITESen_AU
dc.subjectBONDINGen_AU
dc.titleStructural origin of the anisotropic thermal expansion of a K2NiF4-type oxide CaErAlO4 through interatomic distancesen_AU
dc.typeJournal Articleen_AU
dc.date.statistics2016-10-11-
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