Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/7660
Title: What difference does a methyl group make: pentamethylbenzene?
Authors: Mudge, M
NG, BK
Onie, CJ
Bhadbhade, M
Mole, RA
Rule, KC
Stampfl, APJ
Stride, JA
Keywords: Crystals
Radiations
Cadaverine
Reactor lattices
Synchrotrons
Methyl acetate
Issue Date: 11-Sep-2014
Publisher: Wiley Online Library
Citation: Mudge, M., Ng, B. K., Onie, C. J., Bhadbhade, M., Mole, R. A., Rule, K. C., Stampfl, A. P. J. & Stride, J. A. (2014). What difference does a methyl group make: pentamethylbenzene?. ChemPhysChem, 15(17), 3776-3781. doi:10.1002/cphc.201402538
Abstract: The crystal structure of pentamethylbenzene has been obtained for the first time with the use of synchrotron radiation, whilst the low-energy spectrum of lattice dynamics, dominated by the methyl group torsions, was obtained using inelastic neutron scattering. The effect of symmetry lowering by the removal of a single methyl group relative to hexamethylbenzene has been investigated, including the role that this plays in the charge-transfer characteristics of complexes formed with tetracyanoethylene. © 2014, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Gov't Doc #: 7228
URI: http://dx.doi.org/10.1002/cphc.201402538
http://apo.ansto.gov.au/dspace/handle/10238/7660
ISSN: 1439-7641
Appears in Collections:Journal Articles

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