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|Title:||What difference does a methyl group make: pentamethylbenzene?|
|Publisher:||Wiley Online Library|
|Citation:||Mudge, M., Ng, B. K., Onie, C. J., Bhadbhade, M., Mole, R. A., Rule, K. C., Stampfl, A. P. J. & Stride, J. A. (2014). What difference does a methyl group make: pentamethylbenzene?. ChemPhysChem, 15(17), 3776-3781. doi:10.1002/cphc.201402538|
|Abstract:||The crystal structure of pentamethylbenzene has been obtained for the first time with the use of synchrotron radiation, whilst the low-energy spectrum of lattice dynamics, dominated by the methyl group torsions, was obtained using inelastic neutron scattering. The effect of symmetry lowering by the removal of a single methyl group relative to hexamethylbenzene has been investigated, including the role that this plays in the charge-transfer characteristics of complexes formed with tetracyanoethylene. © 2014, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.|
|Gov't Doc #:||7228|
|Appears in Collections:||Journal Articles|
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