Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/7482
Title: Novel chemical synthesis and characterization of CeTi2O6 Brannerite
Authors: Kong, L
Gregg, DJ
Karatchevtseva, I
Zhang, Z
Blackford, MG
Middleburgh, SC
Lumpkin, GR
Triani, G
Keywords: Cerium
Titanates
X-ray diffraction
Thermal analalysis
Electron spectroscopy
Brannerite
Issue Date: 13-Jun-2014
Publisher: ACS Publications
Citation: Kong, L., Gregg, D. J., Karatchevtseva, I., Zhang, Z., Blackford, M. G., Middleburgh, S. C., Lumpkin, G. R., & Triani, G. (2014). Novel chemical synthesis and characterization of CeTi2O6 crannerite. Inorganic Chemistry, 53(13), 6761-6768. doi:10.1021/ic500563j
Abstract: Cerium titanate CeTi2O6 was prepared by a new soft chemistry route in aqueous solution. A suite of characterization techniques, including X-ray diffraction, thermal analysis, vibrational spectroscopy, and scanning and transmission electron spectroscopy, were employed to investigate the brannerite structure formation and its bulk properties. The synthesized powder formed the brannerite crystal structure upon calcination at temperatures as low as 800 °C. Samples sintered at 1350 °C possess a high level of crystallinity. X-ray absorption near-edge structure results indicate the presence of six-coordinated Ce4+ in the brannerite samples. © 2014, American Chemical Society.
Gov't Doc #: 7069
URI: http://dx.doi.org/10.1021/ic500563j
http://apo.ansto.gov.au/dspace/handle/10238/7482
ISSN: 1520-510X
Appears in Collections:Journal Articles

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