Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/5712
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dc.contributor.authorBrant, WR-
dc.contributor.authorSchmid, S-
dc.contributor.authorDu, G-
dc.contributor.authorGu, Q-
dc.contributor.authorSharma, N-
dc.date.accessioned2014-06-24T00:53:36Z-
dc.date.available2014-06-24T00:53:36Z-
dc.date.issued2013-12-15-
dc.identifier.citationBrant, W. R., Schmid, S., Du, G., Gu, Q., & Sharma, N. (2013). A simple electrochemical cell for in-situ fundamental structural analysis using synchrotron X-ray powder diffraction [Special Issue]. Journal of Power Sources, 244, 109-114. doi:10.1016/j.jpowsour.2013.03.086en_AU
dc.identifier.govdoc5424-
dc.identifier.issn10.1016/j.jpowsour.2013.03.086-
dc.identifier.urihttp://dx.doi.org/10.1016/j.jpowsour.2013.03.086en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/5712-
dc.description.abstractA simple in-situ cell design is formulated based on the various in-situ electrochemical cells developed over the last three decades. The cell is targeted at those researchers who are not necessarily in the field of lithium ion battery research but are interested in synthesising and performing fundamental structural analyses of compounds that cannot be made via any other route. Therefore, this design uses only components that are routinely available and can be machined in-house. The effectiveness of the initial cell design is demonstrated through kinetic analysis of the lithium insertion reaction for the Li0.18Sr0.66Ti0.5Nb0.5O3 defect perovskite using data obtained from hundreds of diffraction patterns. Within the first discharge it has been possible to identify three regions with different rates of crystal lattice expansion. These regions extend from 1.01 to 1.47 V, 1.47-1.58 V and 1.58-2.07 V with rates of crystal lattice expansion determined to be 1.765(6) x 10(-5) angstrom min(-1), 1.44(5) x 10(-5) angstrom min(-1) and 2.47(1) x 10(-5) angstrom min(-1), respectively. These three regions correlate with three distinct regions in the electrochemical profile, between 1.00 and 1.36 V, 1.36-1.55 V and 1.55-1.80 V. © 2013, Elsevier Ltd.en_AU
dc.language.isoenen_AU
dc.publisherElsevier Science BVen_AU
dc.subjectX-ray diffractionen_AU
dc.subjectX-ray lasersen_AU
dc.subjectPerovskiteen_AU
dc.subjectLithiumen_AU
dc.subjectBehavioren_AU
dc.subjectDiffractionen_AU
dc.titleA simple electrochemical cell for in-situ fundamental structural analysis using synchrotron X-ray powder diffractionen_AU
dc.typeJournal Articleen_AU
dc.date.statistics2014-06-24-
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