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Title: | The structure of B-type Sm2O3. A powder neutron diffraction study using enriched Sm-154 |
Authors: | Kennedy, BJ Avdeev, M |
Keywords: | Samarium Neutron diffraction Isotopes Crystal lattices Crystals Crystallography |
Issue Date: | 1-Sep-2011 |
Publisher: | Elsevier Science BV |
Citation: | Kennedy, B. J., & Avdeev, M. (2011). The structure of B-type Sm2O3. A powder neutron diffraction study using enriched Sm-154. Solid State Sciences, 13(9), 1701-1703. doi:10.1016/j.solidstatesciences.2011.06.020 |
Abstract: | The structure of Sm(2)O(3) in its B-type monoclinic (C2/m) form has been refined through Rietveld refinement of powder neutron diffraction data. In order to overcome the high absorption cross-section of naturally occurring Sm the Sm-154 was used. The refined structure shows the average coordination of each of the three crystallographically unique Sm sites to be comparable. An un-expected result of this work is the relatively large difference between the refined (8.62 (1) fm) and tabulated (9.30 fm) scattering lengths of Sm-154. Evidently small variations in the precise isotopic composition can significantly alter this value. © 2011, Elsevier Ltd. |
Gov't Doc #: | 4318 |
URI: | http://dx.doi.org/10.1016/j.solidstatesciences.2011.06.020 http://apo.ansto.gov.au/dspace/handle/10238/5618 |
ISSN: | 1293-2558 |
Appears in Collections: | Journal Articles |
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