Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/4055
Full metadata record
DC FieldValueLanguage
dc.contributor.authorSharma, N-
dc.contributor.authorDu, GD-
dc.contributor.authorStuder, AJ-
dc.contributor.authorGuo, ZP-
dc.contributor.authorPeterson, VK-
dc.date.accessioned2012-02-21T05:02:45Z-
dc.date.available2012-02-21T05:02:45Z-
dc.date.issued2011-09-28-
dc.identifier.citationSharma, N., Du, G. D., Studer, A. J., Guo, Z. P., Peterson, V. K. (2011). In-situ neutron diffraction study of the MoS2 anode using a custom-built li-ion battery. Solid State Ionics, 199-200, 37-43. doi:10.1016/j.ssi.2011.07.015en_AU
dc.identifier.govdoc3841-
dc.identifier.issn0167-2738-
dc.identifier.urihttp://dx.doi.org/10.1016/j.ssi.2011.07.015en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/4055-
dc.description.abstractThis work presents the first in-situ neutron diffraction study of the MoS2 electrode, undertaken in a custom-built li-ion battery during discharge. A review of custom-designed cells for in-situ neutron diffraction experiments is presented along with our optimised cell, which we use to show real-time information corresponding to Li-insertion into MoS2 via disappearance of the (103) reflection and increase in the d-spacing of the (002) reflection. The changes in the diffraction patterns begin at the 1.1 V plateau and are complete during the 0.5 V plateau. Sequential Rietveld-refinement indicates the presence of an intermediate lithiated phase (LixMoS2) between MoS2 and LiMoS2. We observe the disappearance of all reflections for the MoS2, corresponding to the loss of long-range order, during the 0.5 V plateau and no new diffraction peaks appear with further electrochemical cycling. This result is indicative of a transformation from long-range ordered MoS2 to short-range ordered LiMoS2, a result that we confirm using ex-situ synchrotron X-ray and neutron diffraction. © 2011, Elsevier Ltd.en_AU
dc.language.isoenen_AU
dc.publisherElsevieren_AU
dc.subjectNeutron diffractionen_AU
dc.subjectAnodesen_AU
dc.subjectRadioisotope batteriesen_AU
dc.subjectLithium ionsen_AU
dc.subjectEnergy storageen_AU
dc.subjectX-ray diffractionen_AU
dc.titleIn-situ neutron diffraction study of the MoS2 anode using a custom-built li-ion batteryen_AU
dc.typeJournal Articleen_AU
dc.date.statistics2012-02-21-
Appears in Collections:Journal Articles

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.