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Title: | Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions |
Authors: | Boyd, PDW Edwards, AJ Gardiner, MG Ho, CC Lemée‐Cailleau , MH McGuinness, DS Riapanitra, A Steed, JW Stringer, DN Yates, BF |
Keywords: | Palladium Homogeneous catalysis Coupling Carbenes Crystal structure Reduction |
Issue Date: | 23-Aug-2010 |
Publisher: | Wiley-VCH Verlag Berlin |
Citation: | Boyd, P. D. W., Edwards, A. J., Gardiner, M. G., Ho, C. C., Lemee-Cailleau, M. H., McGuinness, D. S., Riapanitra, A., Steed, J. W., Stringer, D. N., & Yates, B. F. (2010). Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions. Angewandte Chemie-International Edition, 49(36), 6315-6318. doi:10.1002/anie.201003177 |
Abstract: | The first palladium(I) N-heterocyclic carbene complex has been isolated in high yield by the base-assisted reduction of a palladium(II) precursor. The location of the unique terminal hydride (see picture; PdI cyan, H white, N blue) was established by neutron crystal structure determination, and the solution fluxional behavior of the complex was explored. © 2010, Wiley-VCH Verlag Berlin |
Gov't Doc #: | 2641 |
URI: | http://dx.doi.org/10.1002/anie.201003177 http://apo.ansto.gov.au/dspace/handle/10238/2505 |
ISSN: | 1433-7851 |
Appears in Collections: | Journal Articles |
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