Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/2505
Title: Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions
Authors: Boyd, PDW
Edwards, AJ
Gardiner, MG
Ho, CC
Lemée‐Cailleau , MH
McGuinness, DS
Riapanitra, A
Steed, JW
Stringer, DN
Yates, BF
Keywords: Palladium
Homogeneous catalysis
Coupling
Carbenes
Crystal structure
Reduction
Issue Date: 23-Aug-2010
Publisher: Wiley-VCH Verlag Berlin
Citation: Boyd, P. D. W., Edwards, A. J., Gardiner, M. G., Ho, C. C., Lemee-Cailleau, M. H., McGuinness, D. S., Riapanitra, A., Steed, J. W., Stringer, D. N., & Yates, B. F. (2010). Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions. Angewandte Chemie-International Edition, 49(36), 6315-6318. doi:10.1002/anie.201003177
Abstract: The first palladium(I) N-heterocyclic carbene complex has been isolated in high yield by the base-assisted reduction of a palladium(II) precursor. The location of the unique terminal hydride (see picture; PdI cyan, H white, N blue) was established by neutron crystal structure determination, and the solution fluxional behavior of the complex was explored. © 2010, Wiley-VCH Verlag Berlin
Gov't Doc #: 2641
URI: http://dx.doi.org/10.1002/anie.201003177
http://apo.ansto.gov.au/dspace/handle/10238/2505
ISSN: 1433-7851
Appears in Collections:Journal Articles

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