Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/1872
Title: Central atom size effect on the structure of group 14 tetratolyls.
Authors: Ng, MCC
Craig, DJ
Harper, JB
van Eijck, L
Stride, JA
Keywords: Crystallography
Atoms
Molecular dynamics method
Inelastic scattering
Silicon
Germanium
Issue Date: 6-Jul-2009
Publisher: Wiley-VCH Verlag Berlin
Citation: Ng, M. C. C., Craig, D. J., Harper, J. B., van Eijck, L., & Stride, J. A. (2009). Central atom size effect on the structure of group 14 tetratolyls. Chemistry-a European Journal, 15(27), 6569-6572.
Abstract: Size matters! The structure and dynamics of the tetratolyl Group 14 elements, which were probed by using high-resolution inelastic neutron scattering spectra, show a remarkable dependence on the size of the central atom. The para-methyl groups at the periphery of the molecules constitute the frontier intermolecular interactions of increasingly larger tetrahedra, which becomes critical at the molecular radius of the Si and Ge analogues. © 2009, Wiley-VCH Verlag Berlin
Gov't Doc #: 1307
URI: http://dx.doi.org/10.1002/chem.200900360
http://apo.ansto.gov.au/dspace/handle/10238/1872
ISSN: 0947-6539
Appears in Collections:Journal Articles

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