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|Title:||Inelastic neutron scattering of H-2 adsorbed in HKUST-1.|
|Citation:||Liu, Y., Brown, C. M., Neumann, D. A., Peterson, V. K., & Kepert, C. J. (2007). Inelastic neutron scattering of H-2 adsorbed in HKUST-1. Journal of Alloys and Compounds, 446, 385-388. doi:10.1016/j.jallcom.2006.12.106|
|Abstract:||A series of inelastic neutron scattering (INS) investigations of hydrogen adsorbed in activated HKUST-1 (Cu-3(1,3,5-benzenetricarboxylate)(2)) result in INS spectra with rich features, even at very low loading (< 1.0 H-2:Cu). The distinct inelastic features in the spectra show that there are three binding sites that are progressively populated when the H-2 loading is less than 2.0 H-2:Cu, which is consistent with the result obtained from previous neutron powder diffraction experiments. The temperature dependence of the INS spectra reveals the relative binding enthalpies for H-2 at each site. © 2007, Elsevier Ltd.|
|Gov't Doc #:||1185|
|Appears in Collections:||Journal Articles|
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