Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/10815
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dc.contributor.authorSale, M-
dc.contributor.authorAvdeev, M-
dc.contributor.authorMohamed, Z-
dc.contributor.authorLing, CD-
dc.contributor.authorBarpanda, P-
dc.date.accessioned2021-06-03T04:35:53Z-
dc.date.available2021-06-03T04:35:53Z-
dc.date.issued2017-04-24-
dc.identifier.citationSale, M., Avdeev, M., Mohamed, Z., Ling, C. D., & Barpanda, P. (2017). Magnetic structure and properties of centrosymmetric twisted-melilite K2CoP2O7. Dalton Transactions, 46(19), 6409-6416. doi:10.1039/C7DT00978Jen_US
dc.identifier.issn1477-9234-
dc.identifier.urihttps://doi.org/10.1039/C7DT00978Jen_US
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/10815-
dc.description.abstractTwisted-melilite dipotassium cobalt pyrophosphate (K2CoP2O7, P42/mnm, #136), originally reported by Gabelica-Robert (1981), was synthesized in powder form by a standard solid-state reaction route. The magnetic properties of the material were studied by magnetometry and its magnetic structure determined using neutron powder diffraction for the first time. Below TN = 11 K, the material adopts a G-type antiferromagnetic structure with moments aligned in the ab-plane (magnetic space group Pn′nm, #58.3.473). Ab initio calculations were performed to examine the isotropic magnetic spin exchange parameters as well as the preferred direction of magnetic moments due to spin–orbit coupling. The relationship between crystal structure geometry and the strength of the magnetic interactions was examined and compared to those of melilite-type Sr2CoGe2O7. © The Royal Society of Chemistry 2017en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectMagnetic propertiesen_US
dc.subjectNeutron diffractionen_US
dc.subjectAntiferromagnetic materialsen_US
dc.subjectCrystal structureen_US
dc.subjectMagnetic momentsen_US
dc.subjectSpinen_US
dc.titleMagnetic structure and properties of centrosymmetric twisted-melilite K2CoP2O7en_US
dc.typeJournal Articleen_US
dc.date.statistics2021-05-24-
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