Browsing by Author "Zujovic, Z"

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    “114”-Type nitrides LnAl(Si4−xAlx)N7Oδ with unusual [AlN6] octahedral coordination
    (Wiley, 2017-02-28) Huang, S; Huang, Z; Cao, P; Zujovic, Z; Price, JR; Avdeev, M; Que, M; Suzuki, F; Kido, T; Ouyang, X; Kaji, H; Fang, M; Liu, YG; Gao, W; Söhnel, T
    Aluminum–nitrogen six-fold octahedral coordination, [AlN6], is unusual and has only been seen in the high-pressure rocksalt-type aluminum nitride or some complex compounds. Herein we report novel nitrides LnAl(Si4−xAlx)N7Oδ (Ln=La, Sm), the first inorganic compounds with [AlN6] coordination prepared via non-high-pressure synthesis. Structure refinements of neutron powder diffraction and single-crystal X-ray diffraction data show that these compounds crystallize in the hexagonal Swedenborgite structure type with P63mc symmetry where Ln and Al atoms locate in anticuboctahedral and octahedral interstitials, respectively, between the triangular and Kagomé layers of [SiN4] tetrahedra. Solid-state NMR data of high-purity La-114 powders confirm the unusual [AlN6] coordination. These compounds are the first examples of the “33-114” sub-type in the “114” family. The additional site for over-stoichiometric oxygen in the structure of 114-type compounds was also identified. © 1999-2021 John Wiley & Sons, Inc.
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    Using neutron diffraction to explore lithium displacement within cubic phase stabilised Ga-doped Li6.75La3Zr1.75Ta0.25O12 lithium garnet oxides
    (Elsevier, 2023-12-15) Christopher, TD; Zhang, T; Huang, S; Zujovic, Z; Avdeev, M; Cao, P; Söhnel, T
    Typical Li6.75La3Zr1.75Ta0.25O12 exists as a mixture of tetragonal and cubic arrangements, but adding small amounts of Ga3+ (Li6.75–3xGaxLa3Zr1.75Ta0.25O12 x ≥ 0.1) resulted in a single cubic (I a-3d) phase lithium garnet oxide. Following the stabilisation of the cubic phase, the effects on lithium distributions were explored with neutron powder diffraction concerning Ga3+ content and temperature. Increasing the amount of Ga3+ reduced the amount of lithium within the structure, directly decreasing the Li 96h site occupancy and showing a minimal effect on the Li 24d site occupancy. High-temperature neutron diffraction studies revealed the migration of lithium from the Li 24d site to the Li 96h with increasing temperature. The inclusion of Ga3+ improved the total ionic conductivity over the gallium-free system. However, with increasing gallium content (x > 0.1), a negative correlation between the garnet's gallium content and total lithium ionic conductivity is observed, showing how the total amount of free lithium ions impact the system's total ionic conductivity. Though the electrolytes explored here show some limitations, the lithium-ion displacement trends with doping and temperature give us further insight into how these lithium garnet systems respond to chemical and physical change. © 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY licence.