Browsing by Author "Wei, G"

Now showing 1 - 1 of 1
  • No Thumbnail Available
    Item
    Thorium(IV) and uranium(IV) complexes with cucurbit[5]uril
    (American Chemical Society, 2018-06-27) Zhang, YJ; Bhadbhade, MM; Avdeev, M; Price, JR; Karatchevtseva, I; Li, Q; Tao, Z; Wei, G
    Tetravalent thorium and uranium complexes with cucurbit[5]uril (Q[5]) were investigated with eight new complexes being synthesized and structurally characterized. [Th(Q[5])(OH)(H2O)2]6·18NO3·nH2O (1) has a hexagonal nanowheel structure with each of the six Th4+ ions being cap-coordinated by a Q[5] and monodentate-coordinated to the nearby Q[5]. [Th(Q[5])(HCOO)(H2O)4][Th(NO3)5(H2O)2]2[Th(NO3)3(HCOO)(H2O)2]0.5·NO3·nH2O (2) has a heteroleptic mononuclear structure with a Th4+ ion cap-coordinated on one side of the Q[5] portal and monodentate-coordinated to a formate anion inside the Q[5] cavity. [KTh1.5(Q[5])Cl(NO3)3][Th(NO3)5(H2O)2]·2NO3·2.5H2O (3) has a heterometallic structure with both Th4+ and K+ ions each occupying one side of the two Q[5] portals forming a capsule. [CsTh(Q[5])Cl(NO3)2(H2O)3]·2NO3·nH2O (4) has a heterometallic 1D polymeric structure with both Th4+ and Cs+ ions each occupying one side of the two Q[5] portals, forming monomers which are linked together by sharing two water molecules and one carbonyl oxygen atom between Th4+ and Cs+ ions. [Th(Q[5])Cl(H2O)][CdCl3][CdCl4]·0.5HCl·4H2O (5), [Th(Q[5])Cl(H2O)][Ru2OCl9(H2O)]·0.5HCl·9.5H2O (6), [Th(Q[5])Cl(H2O)][IrCl6]1.5·3H2O (7), and [U(Q[5])Cl(H2O)][ZnCl3(H2O)][(ZnCl4)]·8H2O (8) have similar 1D polymeric structures with Th4+/U4+ ions cap-coordinated on one side of a Q[5] and bidentate coordinated to the nearby Q[5]. The transition metal chlorides act as anions for charge compensation as well as structure inducers via cation–anion interactions forming various anion patterns around the 1D polymers. Actinide contraction has been observed in the early actinide series. © 2018 American Chemical Society