Browsing by Author "Pring, A"

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    Characterization of porosity in sulfide ore minerals: a USANS/SANS study
    (GeoScience World, 2014-11-18) Xia, F; Zhao, J; Etschmann, BE; Brugger, J; Garvey, CJ; Rehm, C; Lemmel, H; Ilavsky, J; Han, YS; Pring, A
    Porosity plays a key role in the formation and alteration of sulfide ore minerals, yet our knowledge of the nature and formation of the residual pores is very limited. Herein, we report the application of ultra-small-angle neutron scattering and small-angle neutron scattering (USANS/SANS) to assess the porosity in five natural sulfide minerals (violarite, marcasite, pyrite, chalcopyrite, and bornite) possibly formed by hydrothermal mineral replacement reactions and two synthetic sulfide minerals (violarite and marcasite) prepared experimentally by mimicking natural hydrothermal conditions. USANS/SANS data showed very different pore size distributions for these minerals. Natural violarite and marcasite tend to possess less pores in the small size range (<100 nm) compared with their synthetic counterparts. This phenomenon is consistent with a higher degree of pore healing or diagenetic compaction experienced by the natural violarite and marcasite. Surprisingly, nanometer-sized (<20 nm) pores were revealed for a natural pyrite cube from La Rioga, Spain, and the sample has a pore volume fraction of ~7.7%. Both chalcopyrite and bornite from the massive sulfide assemblage of the Olympic Dam deposit in Roxby Downs, South Australia, were found to be porous with a similar pore volume fraction (~15%), but chalcopyrite tends to have a higher proportion of nanometer-size pores centered at ~4 nm while bornite tends to have a broader pore size distribution. The specific surface area is generally low for these minerals ranging from 0.94 to 6.28 m2/g, and the surfaces are generally rough as surface fractal behavior was observed for all these minerals. This investigation has demonstrated that USANS/SANS is a very useful tool for analyzing porosity in ore minerals. We believe that with this quantified porosity information a deeper understanding of the complex fluid flow behavior within the porous minerals can be expected. © 2014, Mineralogical Society of America.
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    Developing international radiological risk assessment tools for Australian arid environments
    (South Pacific Environmental Radioactivity Association, 2018-11-06) Popelka-Filcoff, RS; Pring, A; Pandelus, SB; Johns, SM; Tucker, W; Rossouw, D; Lenehan, CE; Hondros, J; Hirth, GA; Carpenter, JG; Johansen, MP; Payne, TE; Roberts, M; Levingstone, K; Tuft, K; Duff, T
    Recent international and Australian regulatory guidance llCRP 108 and ARRANSA Env. Prot. Guide, 2015) has increased the need for effective tools to assess radiological impacts in the environment. The existing internationally accepted methods and models are generally based on data collected in the northern hemisphere and there is a recognised lack of southern hemisphere data, particularly from Australia. When applying the models and methods in Australia, acknowledgement of this lack of data is required which tends to undermine public and regulatory confidence in the assessment. Development of an Australian-specific data set is essential to a better understanding and more credible environmental impact assessment process. In addition, decision-making by operators and regulatory authorities will be based on more relevant local information This presentation describes a collaborative project between university, government and industry researchers and a national industry funding body, aimed at developing a more complete understanding of radiological uptake of native flora and fauna in arid Australian environments. The presentation will cover the framework and sampling and analysis approaches from arid environments, and how these fit into international practice. lnitial data and concentration ratios from analysis of Dodonaea viscosa and Acacia ligulata, rabbits and feral cats and corresponding soil will be presented. Analytical methods include high-resolution gamma spectroscopy with low limits of detection, alpha spectroscopy, elemental analysis by inductively coupled plasma mass spectrometry, scanning electron microscopy. ant"; 3."; 5 Novel approaches to data collection and analysis protocols are used, which form the basis of the databases use: :. i"e internationally accepted models and comparison to extant studies. The project lays the infrastructure towards an effective Australian intenface with existing tools (e.g. ERICA) and assessment for extended long-term studies for industry and regulators. The results of this project build a foundation for environmental radionuclide assessment for Australia's specific climate and species, and build a framework for a comprehensive Australian context and understanding of radionuciides and their concentration ratios as well as towards screening levels which may vary depending on location and species. This project has an industry-wide impact in the generation of robust data sets towards modelling in arid environments.
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    A large volume cell for in situ neutron diffraction studies of hydrothermal crystallizations
    (American Institute of Physics, 2010-10-19) Xia, F; Qian, GJ; Brugger, J; Studer, AJ; Olsen, SR; Pring, A
    A hydrothermal cell with 320 ml internal volume has been designed and constructed for in situ neutron diffraction studies of hydrothermal crystallizations. The cell design adopts a dumbbell configuration assembled with standard commercial stainless steel components and a zero-scattering Ti–Zr alloy sample compartment. The fluid movement and heat transfer are simply driven by natural convection due to the natural temperature gradient along the fluid path, so that the temperature at the sample compartment can be stably sustained by heating the fluid in the bottom fluid reservoir. The cell can operate at temperatures up to 300 °C and pressures up to 90 bars and is suitable for studying reactions requiring a large volume of hydrothermal fluid to damp out the negative effect from the change of fluid composition during the course of the reactions. The capability of the cell was demonstrated by a hydrothermal phase transformation investigation from leucite (KAlSi2O6) to analcime (NaAlSi2O6⋅H2O) at 210 °C on the high intensity powder diffractometer Wombat in ANSTO. The kinetics of the transformation has been resolved by collecting diffraction patterns every 10 min followed by Rietveld quantitative phase analysis. The classical Avrami/Arrhenius analysis gives an activation energy of 82.3±1.1 kJ mol−1. Estimations of the reaction rate under natural environments by extrapolations agree well with petrological observations. © 2010, American Institute of Physics
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    Microporous gold: comparison of textures from nature and experiments
    (American Mineralogist, 2014-05-15) Okrugin, VM; Andreeva, E; Etschmann, BE; Pring, A; Li, P; Zhao, J; Griffiths, GJ; Lumpkin, GR; Triani, G; Brugger, J
    Recent experiments have shown that microporous gold can be obtained via the oxidative dealloying of Au(Ag)-tellurides such as calaverite (AuTe2), krennerite (Au3AgTe8), and sylvanite [(Au,Ag)2Te4] under mild hydrothermal conditions. The same Au textures have been found in natural gold-telluride ores from the Late Miocene epithermal Aginskoe Au-Ag-Te deposit in Kamchatka, Russia. This confirms that natural microporous gold can form via the replacement of telluride minerals. This replacement may take place under hydrothermal conditions, e.g., during the late stage of the ore-depositing event, explaining the wide distribution of “mustard gold” in some deposits. At Aginskoe, the oxidation of Au-tellurides appears to have resulted only in local redistribution of Au and Te, because the associated oxidation of chalcopyrite scavenged the excess Te, inhibiting the crystallization of secondary Te minerals more than a few micrometers in size. Such cryptic mobility may explain the lack of reported secondary Te minerals in many Te-bearing deposits. © 2014, Mineralogical Society of America.
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    Phase analysis of Australian uranium ore concentrates determined by variable temperature synchrotron powder x-ray diffraction
    (American Chemical Society, 2021-07-22) Pandelus, SB; Kennedy, BJ; Murphy, GL; Brand, HEA; Keegan, EA; Pring, A; Popelka-Filcoff, RS
    The chemical speciation of uranium oxides is sensitive to the provenance of the samples and their storage conditions. Here, we use diffraction methods to characterize the phases found in three aged (>10 years) uranium ore concentrates of different origins as well as in situ analysis of the thermally induced structural transitions of these materials. The structures of the crystalline phases found in the three samples have been refined, using high-resolution synchrotron X-ray diffraction data. Rietveld analysis of the samples from the Olympic Dam and Ranger uranium mines has revealed the presence of crystalline α-UO2(OH)2, together with metaschoepite (UO2)4O(OH)6·5H2O, in the aged U3O8 samples, and it is speculated that this forms as a consequence of the corrosion of U3O8 in the presence of metaschoepite. The third sample, from the Beverley uranium mine, contains the peroxide [UO2(η2-O2)(H2O)2] (metastudtite) together with α-UO2(OH)2 and metaschoepite. A core–shell model is proposed to account for the broadening of the diffraction peaks of the U3O8 evident in the samples. © 2021 American Chemical Society
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    A thermosyphon-driven hydrothermal flow-through cell for in situ and time-resolved neutron diffraction studies
    (Wiley-Blackwell, 2010-06-01) Xia, F; O'Neill, B; Ngothai, Y; Peak, J; Tenailleau, C; Etschmann, BE; Qian, G; Brugger, J; Studer, AJ; Olsen, SR; Pring, A
    A flow-through cell for hydrothermal phase transformation studies by in situ and time-resolved neutron diffraction has been designed and constructed. The cell has a large internal volume of 320 ml and can operate at temperatures up to 573 K under autogenous vapor pressures (ca 8.5 × 106 Pa). The fluid flow is driven by a thermosyphon, which is achieved by the proper design of temperature difference around the closed loop. The main body of the cell is made of stainless steel (316 type), but the sample compartment is constructed from non-scattering Ti-Zr alloy. The cell has been successfully commissioned on Australia's new high-intensity powder diffractometer WOMBAT at the Australian Nuclear Science and Technology Organization, using two simple phase transformation reactions from KAlSi2O6 (leucite) to NaAlSi2O6·H2O (analcime) and then back from NaAlSi2O6·H2O to KAlSi2O6 as examples. The demonstration proved that the cell is an excellent tool for probing hydrothermal crystallization. By collecting diffraction data every 5 min, it was clearly seen that KAlSi2O6 was progressively transformed to NaAlSi2O6·H2O in a sodium chloride solution, and the produced NaAlSi2O6·H2O was progressively transformed back to KAlSi2O6 in a potassium carbonate solution. © 2010, Wiley-Blackwell.