Browsing by Author "Prescimone, A"

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    [Mn-6] under pressure: a combined crystallographic and magnetic study
    (Wiley-VCH Verlag Berlin, 2008-03) Prescimone, A; Milios, CJ; Moggach, S; Warren, JE; Lennie, AR; Sanchez-Benitez, J; Kamenev, KV; Bircher, R; Murrie, M; Parsons, S; Brechin, EK
    Folding under pressure: High-pressure crystallography of an Mn6 single-molecule magnet reveals dramatic changes in the intramolecular geometry of the magnetic core. These structural changes effect the magnetic properties of the molecule: the magnitude of the ferromagnetic exchange between the metals is decreased, and under extreme pressure switches to antiferromagnetic. © 2008, Wiley-VCH Verlag Berlin