Browsing by Author "Moy, AD"
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- ItemCharacterizing black carbon in rain and ice cores using coupled tangential flow filtration and transmission electron microscopy(European Geosciences Union, 2015-01-01) Ellis, A; Edwards, R; Saunders, M; Chakrabarty, RK; Subramanian, R; van Riessen, A; Smith, AM; Lambrinidis, D; Nunes, LJ; Vallelonga, P; Goodwin, ID; Moy, AD; Curran, MAJ; van Ommen, TDAntarctic ice cores have been used to study the history of black carbon (BC), but little is known with regards to the physical and chemical characteristics of these particles in the remote atmosphere. Characterization remains limited by ultra-trace concentrations in ice core samples and the lack of adequate methods to isolate the particles unaltered from the melt water. To investigate the physical and chemical characteristics of these particles, we have developed a tangential flow filtration (TFF) method combined with transmission electron microscopy (TEM). Tests using ultrapure water and polystyrene latex particle standards resulted in excellent blanks and significant particle recovery. This approach has been applied to melt water from Antarctic ice cores as well as tropical rain from Darwin, Australia with successful results: TEM analysis revealed a variety of BC particle morphologies, insoluble coatings, and the attachment of BC to mineral dust particles. The TFF-based concentration of these particles has proven to give excellent results for TEM studies of BC particles in Antarctic ice cores and can be used for future studies of insoluble aerosols in rainwater and ice core samples. © Author(s)
- ItemDating Antarctic ice cores using high-temporal resolution black carbon records(Antarctic Climate and Ecosystems Cooperative Research Centre, 2016-03-07) Edwards, R; Vallelonga, P; McConnell, JR; Bertler, NAN; Curran, MAJ; Sigil, M; Fudge, TJ; Anschuetz, H; Neff, PD; Emanuelsson, D; Bisiaux, M; Goodwin, D; Smith, AM; Taylor, KC; Moy, AD; Fetieng, W; Ellis, ABlack carbon aerosols (BC) emitted by fires in the Southern Hemisphere (SH) are transported to Antarctica and preserved in the Antarctic ice sheet. Recent efforts to develop ice core records of BC deposition to Antarctica show variability in BC over a broad range of time scales. The ~ monthly-resolution BC record from the WAIS divide deep ice core displayed strong seasonal variability in modern sections of the record consistent with the timing of SH biomass burning. The record was subsequently used as an annual layer dating proxy in conjunction with other chemical species. If the emissions and transport of BC to Antarctica are stable over long periods of time it may be useful as an annual layer proxy at sites other than WAIS. To date, a rigorous comparison of Antarctic ice core BC seasonality from different locations have not been conducted. Here we present a comparison of BC ice core data from the top sections of the WAIS divide deep core, the Roosevelt Island RICE core, and the Law Dome DSS1213 core. The RICE and Law Dome sites are separated from WAIS by large distances and experience different atmospheric circulation and climate regimes. A detailed description of the data uncertainties and its use in annual layer counting will be discussed.
- ItemIndividual particle morphology, coatings, and impurities of black carbon aerosols in Antarctic ice and tropical rainfall(John Wiley & Sons, Inc, 2016-11-04) Ellis, A; Edwards, R; Saunders, M; Chakrabarty, RK; Subramanian, R; Timms, NE; van Riessen, A; Smith, AM; Lambrindis, D; Nunes, LJ; Vallelonga, P; Goodwin, ID; Moy, AD; Curran, MAJ; van Ommen, TDBlack carbon (BC) aerosols are a large source of climate warming, impact atmospheric chemistry, and are implicated in large-scale changes in atmospheric circulation. Inventories of BC emissions suggest significant changes in the global BC aerosol distribution due to human activity. However, little is known regarding BC's atmospheric distribution or aged particle characteristics before the twentieth century. Here we investigate the prevalence and structural properties of BC particles in Antarctic ice cores from 1759, 1838, and 1930 Common Era (C.E.) using transmission electron microscopy and energy-dispersive X-ray spectroscopy. The study revealed an unexpected diversity in particle morphology, insoluble coatings, and association with metals. In addition to conventionally occurring BC aggregates, we observed single BC monomers, complex aggregates with internally, and externally mixed metal and mineral impurities, tar balls, and organonitrogen coatings. The results of the study show BC particles in the remote Antarctic atmosphere exhibit complexity that is unaccounted for in atmospheric models of BC. ©2016. American Geophysical Union.
- ItemModern to Glacial Age subglacial meltwater drainage at Law Dome, coastal East Antarctica from topography, sediments and jökulhlaup observations(The Geological Society of London, 2017-07-12) Goodwin, ID; Roberts, JL; Etheridge, DM; Hellstrom, JC; Moy, AD; Ribo, M; Smith, AMRare jökulhlaup events, also known as subglacial lake outburst flood events, have been observed at the Law Dome ice margin and provide an insight into the physical characteristics of subglacial meltwater and drainage. The subglacial topography based on data from the BEDMAP2 and ICECAP projects, together with subsurface transects of the ice margin obtained using ground-penetrating radar, reveal several lakes and lake-like depressions and the drainage pathways of two jökulhlaup events. Oxygen isotope typing of the meltwater during the most recent (2014) jökulhlaup event, combined with ice margin stratigraphy, enable the identification of ice tunnel melt pathways that exploit the 30–90° dipping basal ice layering. The presence of subglacial meltwater beneath Law Dome during the Holocene to Glacial periods is confirmed by the dendritic drainage pattern in the subglacial morphology and extensive layers of basal regelation ice and subglacial carbonate precipitate deposits found within the Løken Moraines sediments. These subglacial carbonates, including ooid layers, formed from the mixing of glacial meltwater and seawater at 72 ka BP. The combined evidence indicates that the ocean discharge of subglacial meltwater may be variable and/or is periodically blocked by basal freezing events near the ice sheet terminus. © 2018 The Author(s). Published by The Geological Society of London.
- ItemA quasi-monthly record of 10Be concentration at Law Dome, Antarctica, from 2000 to 2015(Antarctic Climate and Ecosystems Cooperative Research Centre, 2016-03-07) Smith, AM; Curran, MAJ; Etheridge, DM; Galton-Fenzi, BK; Heikkilä, UE; Klekociuk, AR; Moy, AD; Pedro, JB; Simon, KJ; van Ommen, TDThis paper presents an overview of work undertaken over a number of Australian Antarctic Science projects, beginning in season 2001/02 with a shallow snow pit. In season 2005/06 this was augmented with a 260 m thermally drilled ice core and a 4.5 m snow pit. A core taken in 2008/09 overlapped the 2005/06 core and pit samples. From 2009/10, short cores spanning a few year’s deposition, along with snow pit samples spanning about half a year, have been taken each season. This has continued through to the current 2015/16 season. The cores permit an overlap with earlier years to match the chronology and to yield samples for 10Be analysis at the Australian Nuclear Science and Technology Organisation (ANSTO) by the technique of accelerator mass spectrometry (AMS). Together, the data provide a unique, continuous, quasi-monthly record over 2000 to 2015 as we have moved from Solar Cycle 23 to 24. The snow pits yield larger samples for 7Be analysis, earlier by gamma spectroscopy but lately by AMS. Along with comparison with neutron monitor data and GCM modelling, this unique, high-precision record has enabled us to learn much about the production, transport and deposition of 10Be to Law Dome and to improve our use of 10Be as a proxy for past solar variability.
- ItemSolar and climate influences on ice core 10Be records from Antarctica and Greenland during the neutron monitor era(Elsevier, 2012-11-15) Pedro, JB; McConnell, JR; van Ommen, TD; Fink, D; Curran, MAJ; Smith, AM; Simon, KJ; Moy, AD; Das, SBCosmogenic 10Be in polar ice cores is a primary proxy for past solar activity. However, interpretation of the 10Be record is hindered by limited understanding of the physical processes governing its atmospheric transport and deposition to the ice sheets. This issue is addressed by evaluating two accurately dated, annually resolved ice core 10Be records against modern solar activity observations and instrumental and reanalysis climate data. The cores are sampled from the DSS site on Law Dome, East Antarctica (spanning 1936–2009) and the Das2 site, southeast Greenland (1936–2002), permitting inter-hemispheric comparisons. Concentrations at both DSS and Das2 are significantly correlated to the 11-yr solar cycle modulation of cosmic ray intensity, rxy=0.54 with 95% CI [0.31; 0.70], and rxy=0.45 with 95% CI [0.22; 0.62], respectively. For both sites, if fluxes are used instead of concentrations then correlations with solar activity decrease. The strength and spectral coherence of the solar activity signal in 10Be is enhanced when ice core records are combined from both Antarctica and Greenland. The amplitudes of the 11-yr solar cycles in the 10Be data appear inconsistent with the view that the ice sheets receive only 10Be produced at polar latitudes. Significant climate signals detected in the 10Be series include the zonal wave three pattern of atmospheric circulation at DSS, rxy=−0.36 with 95% CI [−0.57; −0.10], and the North Atlantic Oscillation at Das2, rxy=−0.42 with 95% CI [−0.64; −0.15]. The sensitivity of 10Be concentrations to modes of atmospheric circulation advises caution in the use of 10Be records from single sites in solar forcing reconstructions. © 2012 Elsevier B.V.