Browsing by Author "Lopes, DA"
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- ItemAnisotropy in the thermal expansion of uranium silicide measured by neutron diffraction(Elsevier, 2018-09) Obbard, EG; Johnson, KD; Burr, PA; Lopes, DA; Liss, KD; Griffiths, GJ; Scales, N; Middleburgh, SCIn-situ neutron diffraction patterns were collected for a sample of as-cast U3Si2 during heating to 1600 °C. Anomalous changes were observed above 1000 °C, including the formation of a new diffraction peak not belonging to P4/mbm U3Si2, unequal changes in the peak intensities and onset of anisotropic lattice expansion. The large data-set enabled derivation of a function-fitted isotropic thermal expansion coefficient to high precision, in close agreement with previous dilatometry results but reducing linearly with temperature over the studied interval. Anisotropy in the instantaneous lattice thermal expansion corresponded to anomalies reported by White et al. (2015) at a similar temperature. © Elsevier B.V
- ItemIn-situ neutron characterization of advanced nuclear ruels - the road to a new neutron irradiation testing capability(The Minerals, Metals & Materials Society, 2020-02-23) Obbard, EG; Gasparrini, C; Burr, PA; Johnson, KD; Lopes, DA; Anghel, C; Middleburgh, SC; Gregg, DJ; Liss, KD; Griffiths, GJ; Scales, N; Thorogood, GJ; Lumprin, GRNot available.
- ItemThermal expansion and steam oxidation of uranium mononitride analysed via in situ neutron diffraction(Elsevier B. V., 2023-03) Liu, J; Gasparrini, C; White, JT; Johnson, KD; Lopes, DA; Peterson, VK; Studer, AJ; Griffiths, GJ; Lumpkin, GR; Wenman, MR; Burr, PA; Sooby, ES; Obbard, EGIn situ neutron powder diffraction experiments are applied to physical, kinetic, and microstructural characterization of uranium mononitride as a promising light water reactor fuel material. The temperature-variable coefficient of thermal expansion and isotropic Debye Waller factors are obtained by sequential Rietveld refinement over 499–1873 K. Oxidation of a UN pellet (95.2% density) under flow of 11 mg/min D2O is observed to initiate above 623 K and the rate increases by a factor of approximately 10 from 673 to 773 K, with activation energy 50.6 ± 1.3 kJ/mol; uranium oxide is the only solid corrosion product. Crown Copyright © 2022 Published by Elsevier B.V.