Browsing by Author "Greig, A"
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- ItemA 1,000 year rainfall record for SE Australia using speleothem hydrological proxies(Geological Society of Australia, 2010-07-04) McDonald, J; Drysdale, RN; Hodge, E; Hua, Q; Fischer, MJ; Treble, PC; Greig, A; Hellstrom, JCCave drip water studies at Wombeyan Caves (34°19’S, 149°59’E) demonstrated a marked hydrochemical response to wet/dry (McDonald et al., 2004; 2007). Three 20th Century coeval active speleothems (WM4, WM6 and WM20) were geochemically analysed and changes in trace element and stable isotope values were related to the instrumental record. These climate‐geochemical relationships were interpolated to two longrecord speleothems (WM7 and WM9) which grew deeper within the same cave system. Two major difficulties were encountered. Unlike other sub‐annual/annual climate records derived from speleothems using trace elements (Treble et al., 2003; Johnson et al., 2006); stable isotopes (Treble et al., 2005; Johnson et al., 2006) and annual laminae (Borsato et al., 2007) where annual cycles were shown to be consistent, at Wombeyan frequent droughts perturb predicted rainfall patterns and rainfall variability is high. Here, droughts can span several years, or extend over winter, diminishing or obliterating the expected winter recharge signal. Alternatively, wet summers can sustain ‘unseasonal’ high discharge and lessen the expected prior calcite precipitation (PCP) signal. Thus an annual wet/dry geochemical signal is often absent. Secondly, due to the young age of the speleothems and very low uranium concentrations (~10 ppb) the use of U‐series disequilibrium dating was ineffective to produce a robust chronology. Trace element cycle counting only gave the minimum age due to the non‐expression of many cycles. The 14C bomb pulse was successfully defined in two modern stalagmites (WM4 and WM6) and maximum 14‐C activity was around 134 per cent modern carbon (pMC) for both speleothems, indicating rapid transfer of 14‐C from atmosphere, to soil, to drip water during the bomb‐pulse period. A dampened 14C bomb pulse was detected in WM7 (where pMCmax was 112 per cent modern carbon) reflecting the greater degree of mixing within the thicker bedrock. Carbon‐14 AMS analyses were utilised together with trace element cycle counting to obtain preliminary chronological control. Despite these difficulties, palaeohydrological records using multiple proxies: Mg/Ca (aridity), P and Y (wet), δ18O (dominant air mass and rainfall amount signals), and based on 14C ages were constructed for the longerrecord, slower growing stalagmites. Over the last 1,000 years there have been several sustained episodes of wet/arid or highly variable phases. A sustained wet phase occurred ~ 900–1300 AD and followed by ~ 200 years of highly variable wet/dry conditions. From ~ 1500 to 1800 AD a dry phase is indicated. The last 150 years support a drying phase, but the negative IPO (1944–1978 [wettest period in 20thC]) is not indicated by a negative anomaly and further, sustained positive δ18O anomalies in this period suggest that other factors maybe influencing this part of the record (temperature?). The δ18O record indicates changing frequency from ~ centennial to pentadecadal time‐scales in the longer‐time scale oscillations. Within the longer‐time scale oscillations, higher resolution (~ 2–5 years) variability is evident replicating the trend shown by modern annually resolved stalagmites at this site.
- ItemA 1,500 year south Australian rainfall record based on speleothem hydrological proxies(AMOS National Conference, 2013-02-11) McDonald, J; Drysdale, RN; Hua, Q; Hodge, E; Treble, PC; Greig, A; Fallon, SJ; Lee, S; Hellstrom, JCCave drip water studies at Wombeyan Caves (34°19’S, 149°59’E) demonstrated a marked hydrochemical response to wet/dry phases (McDonald Et al. 2004; 2007). Geochemical Variations in three 20th Century coeval active Speleothems were able to be linked to the instrumental record. Subsequently geochemical relationships were investigated in a long record speleothem(WM7) which grew deeper within the same cave system. Obtaining a robust chronology proved to be challenging, due to the young age of the speleothem and very low uranium concentrations (~10 ppb) the use of U‚Aeseries disequilibrium dating was ineffective to produce a robust chronology. Chronology for WM7 was based on a dense sequence of DCF corrected ages using three different age-‐depth models: Clam (Classical method), and Bacon and OxCal (Bayesian statistical approach) (Hua et al. 2012).The new chronology indicated that WM7 began growth around 4400 cal BP(171 mm). However, since sampling from 0-‐50mm was most intensive, the model is based on this part of the stalagmite and indicates that the top 50 mm of WM7 grew during the past 1360 and 1740 years. An aridity index based on Sr,P, Y, La, and Ba shows that over the last 1,500 years several sustained episodes of wet/arid and otherwise variable phases have occurred. Two sustained wet phases ~ 700-‐880 AD and ~ 900-‐ 1250 AD were followed by ~ 400 years of variable wet/dry conditions, although from ~1300 to 1600 AD a drying trend is indicated, but punctuated by several wetter episodes. The last 200 years indicate sustained drying phases. The OE￥13C record is anomalous from ~ 1880 to present and attributed to the stalagmite’s recording of increasing contribution of fossil fuel to CO2 concentrations. Within the longer-‐time scale oscillations, higher resolution (~ 2-‐5 years) variability is evident, replicating the trend shown by modern annually resolved stalagmites at this site.
- ItemExceptional datolite crystals from Albion Park, New South Wales: morphology, chemistry and likely origin(Mineralogical Society of Victoria, 2018) Graham, IT; Colchester, DM; Cendón, DI; Lay, A; Hergt, JM; Greig, A; Larsen, JRLarge, well-formed, semi-transparent yellow–green crystals up to 5.6 cm were found in cavities within the Late Permian Bumbo Latite Member of the Gerringong Volcanics in the now abandoned Cleary Brothers Quarry, Albion Park, New South Wales. Although labelled by the collector as calcite, these were later identified as datolite, with two distinct habits, occurring on a matrix of crystallized quartz and prehnite. The datolite contains very low concentrations of elements other than the essential calcium, silicon, oxygen and boron. Its distinctive chondrite-normalized, positive europium anomaly, when compared with datolite data from elsewhere, suggests crystallization from postdiagenetic hydrothermal fluids in the temperature range of 200–250°C. These datolite crystals are the finest ever found in Australia and rank highly with those found elsewhere in the world. © 2018 Mineralogical Society of Victoria
- ItemFast high-resolution synchrotron micro-XRF mapping of annually laminated stalagmites(Copernicus GmbH, 2019-04-11) Borsato, A; Frisia, S; Hellstrom, JC; Treble, PC; Johnson, K; Howard, DL; Greig, AAnnual lamination in trace elements content allows to improve speleothem chronology as well as to extract paleoclimate information about fluctuations of the seasonal signal through time. Given the relatively slow growth and textural heterogeneity intrinsic in most speleothems, only high-resolution mapping techniques provide a viable approach to resolve trace elements variability at annual to sub-annual scale. Synchrotron radiation X-ray fluorescence microscopy (SR-μXRF) is, to date, the ideal technique as it provides quantitative, non-destructive fast scanning of large samples at the necessary high spatial resolution (0.5 – 5 μm). Here we present SR-μXRF investigation of U/Th dated stalagmites from caves in different geographic and climate setting including semi-arid (Flinders Ranges, South Australia), temperate (Central Italy) and tropical humid (Cook Islands, Northern Laos) climates. SR-μXRF analyses were coupled with high-resolution petrographic observation and LA-ICP-MS elemental analyses in order to verify the XRF elemental quantification and to test the relationship between fabric and trace element incorporation. All the analysed stalagmites revealed faint to sharp annual lamination in Sr, and, occasionally, in other elements such as Br, Cu and Zn. In climate setting characterised by strong seasonal contrast stalagmites often exhibit fabric changes at annual to centennial scale that are reflected in the internal porosity as well as in the incorporation of trace elements. Fabric control and spatial heterogeneity is also evident in the intensity of the annual cycles and, in some cases, the amplitude of Sr cycles vary considerably from one line scan to the adjacent ones. This poses the question of the significance and reproducibility of trace element analyses in speleothems characterised by fabric heterogeneity. © Author(s) 2019. CC Attribution 4.0 license.
- ItemPartitioning of Mg, Sr, Ba and U into a subaqueous calcite speleothem(Elsevier, 2019-11-01) Drysdale, RN; Zanchetta, G; Baneschi, I; Guidi, M; Isola, I; Couchoud, I; Piccini, L; Greig, A; Wong, HKY; Woodhead, JD; Regattieri, E; Corrick, E; Paul, B; Spötl, C; Denson, E; Gordon, J; Jaillet, S; Dux, F; Hellstrom, JCThe trace-element geochemistry of speleothems is becoming increasingly used for reconstructing palaeoclimate, with a particular emphasis on elements whose concentrations vary according to hydrological conditions at the cave site (e.g. Mg, Sr, Ba and U). An important step in interpreting trace-element abundances is understanding the underlying processes of their incorporation. This includes quantifying the fractionation between the solution and speleothem carbonate via partition coefficients (where the partitioning (D) of element X (DX) is the molar ratio [X/Ca] in the calcite divided by the molar ratio [X/Ca] in the parent water) and evaluating the degree of spatial variability across time-constant speleothem layers. Previous studies of how these elements are incorporated into speleothems have focused primarily on stalagmites and their source waters in natural cave settings, or have used synthetic solutions under cave-analogue laboratory conditions to produce similar dripstones. However, dripstones are not the only speleothem types capable of yielding useful palaeoclimate information. In this study, we investigate the incorporation of Mg, Sr, Ba and U into a subaqueous calcite speleothem (CD3) growing in a natural cave pool in Italy. Pool-water measurements extending back 15 years reveal a remarkably stable geochemical environment owing to the deep cave setting, enabling the calculation of precise solution [X/Ca]. We determine the trace element variability of ‘modern’ subaqueous calcite from a drill core taken through CD3 to derive DMg, DSr, DBa and DU then compare these with published cave, cave-analogue and seawater-analogue studies. The DMg for CD3 is anomalously high (0.042 ± 0.002) compared to previous estimates at similar temperatures (∼8 °C). The DSr (0.100 ± 0.007) is similar to previously reported values, but data from this study as well as those from Tremaine and Froelich (2013) and Day and Henderson (2013) suggest that [Na/Sr] might play an important role in Sr incorporation through the potential for Na to outcompete Sr for calcite non-lattice sites. DBa in CD3 (0.086 ± 0.008) is similar to values derived by Day and Henderson (2013) under cave-analogue conditions, whilst DU (0.013 ± 0.002) is almost an order of magnitude lower, possibly due to the unusually slow speleothem growth rates (<1 μm a−1), which could expose the crystal surfaces to leaching of uranyl carbonate. Finally, laser-ablation ICP-MS analysis of the upper 7 μm of CD3, regarded as ‘modern’ for the purposes of this study, reveals considerable heterogeneity, particularly for Sr, Ba and U, which is potentially indicative of compositional zoning. This reinforces the need to conduct 2D mapping and/or multiple laser passes to capture the range of time-equivalent elemental variations prior to palaeoclimate interpretation. © 2019 Elsevier Ltd
- ItemSkeletal arsenic of the pre-Columbian population of Caleta Vitor, northern Chile(Elsevier B.V., 2015-06-01) Swift, J; Cupper, ML; Greig, A; Westaway, MC; Carter, C; Santoro, CM; Wood, R; Jacobsen, GE; Bertuch, FExposure to toxic arsenic has severe health consequences for past and present societies. This research resolves changes in a pre-Industrial population's exposure to the toxin within an arsenic-endemic area of the Atacama Desert of northern Chile over long timescales. Inductively coupled plasma mass spectrometry (ICP-MS) trace element analysis of human bone and tooth samples from 21 burials at Caleta Vitor on the Pacific coast of northern Chile has established that the pre-Columbian inhabitants were exposed to elevated levels of arsenic where one third of the sample population had accumulated levels in their skeletal system indicative of chronic poisoning. Coupled with new accelerator mass spectrometry (AMS) radiocarbon ages for the skeletal samples, spanning c. 3867 to 474 cal BP and encompassing all major cultural periods of the region, these results demonstrate the continual risk of arsenic poisoning over several millennia of occupation at one site. Numerous factors may have partially contributed to the population's inferred poisoning, due to the complex interaction of various environmental sources of arsenic and human behaviours. Increased exposure to arsenic could relate to climatic variability influencing sources of drinking water or anthropogenic activities such as mining and metallurgy or dietary changes associated with agriculture. Assessment of these potential sources of arsenic toxication, including evaluation of modern environmental data from the region, suggests contaminated drinking water was the most likely cause of arseniasis. © 2015 Elsevier Ltd.