Browsing by Author "Giri, P"

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    Migration and formation of an iron rich layer during acidic corrosion of concrete with no steel reinforcement
    (Elsevier, 2021-11-22) Taheri, S; Giri, P; Ams, M; Bevitt, JJ; Bustamante, H; Madadi, M; Kuen, T; Gonzalez, J; Vorreiter, L; Withford, M; Clark, SM
    The present study aimed to study the formation, enrichment, and relocation of iron-rich regions in the corroded area of concrete blocks, made without rebar, subjected to severely corrosive highly acidic conditions. In this work, three different concrete mix designs (a proprietary ready-mixed concrete, and laboratory made mortar and concrete) were corroded under induced accelerated conditions in sulfuric acid solutions at pH 1 for a duration of one to six months, in the absence of reinforcement (i.e. rebar) or iron-oxidizing bacteria. A variety of physicochemical and mechanical techniques were applied to monitor and assess the corrosion progress, and physical and chemical changes in the corroded samples. Results indicated a pronounced presence of iron rich layer (iron oxide/hydroxide) at the border of the corrosion front and the transition zone in all mix designs in the form of a ring. While existing papers in the literature describe the iron coming from the rebar, the only source of mobile iron in this experiment was from the iron oxide (Fe2O3) already in the cement. This zone (in a form of a ring) had an average iron content of 2.0 wt% and moved away from the surface to the center of the samples submerged in a sulfuric acid bath with the increase of immersion time, and it was accompanied by hairline cracks. The movement of this zone was in the same direction as sulfate (from acidic media) ingress and the opposite direction of calcium ion leaching, (Ca leaching). The rate of corrosion, the hardness and the compressive strength of concrete are mostly affected by the concrete mix design, the iron-ring enrichment and relocation had no significant impact on them. Detection of the iron-rich zone is an indication of the depth of corrosion at advanced stages in concrete products. © 2021 Elsevier Ltd
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    Optimisation of a neutron imaging system using the modulation transfer function
    (Elsevier, 2023-12) Grigorova, V; Giri, P; Bevitt, JJ; Clark, SM
    The use of the modulation transfer function was explored for the characterisation and optimisation of the optical system used for tomographic imaging on the DINGO instrument at the Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation, Lucas Heights, Australia. Both a Siemens star and a phantom were used to determine the modulation transfer function and the results are compared. This allowed the optimal configuration of the instrument to be determined and the establishment of a relationship between sample dimension, exposure time and radiograph resolution to be developed. For tomographic studies of large samples, best results were achieved with DINGO configured in high-flux mode (L/D = 500), with a 6LiF/ZnS scintillator screen, an Iris 15TM sCMOS detector, a 50 mm lens, and an exposure time between 4 and 8 s. © 2023 The Authors. Published by Elsevier B.V. - Open Access CC-BY.