Browsing by Author "Fujimoto, D"

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    Direct measurements of the temperature, depth and processing dependence of phenyl ring dynamics in polystyrene thin films by β-detected NMR
    (Royal Society of Chemistry, 2018-05-24) McKenzie, I; Chai, Y; Cortie, DL; Forrest, JA; Fujimoto, D; Karner, VL; Kiefl, RF; Levy, CDP; MacFarlane, WA; McFadden, RML; Morris, GD; Pearson, MR; Zhu, S
    There is indirect evidence that the dynamics of a polymer near a free surface are enhanced compared with the bulk but there are few studies of how dynamics varies with depth. β-Detected nuclear spin relaxation of implanted 8Li+ has been used to directly probe the temperature and depth dependence of the γ-relaxation mode, which is due to phenyl rings undergoing restricted rotation, in thin films of atactic deuterated polystyrene (PS-d8) and determine how the depth dependence of dynamics is affected by sample processing, such as annealing, floating on water and the inclusion of a surfactant, and by the presence of a buried interface. The activation energy for the γ-relaxation process is lower near the free surface. Annealing the PS-d8 films and then immersing in water to mimic the floating procedure used to transfer films had negligible effects on the thickness of the region near the free surface with enhanced mobility. Measurements on a bilayer film indicate enhanced phenyl ring dynamics near the buried interface compared with a single film at the same depth. PS-d8 films annealed with the surfactant sodium dodecyl sulfate (SDS) deposited on the surface show enhanced dynamics in the bulk compared with a pure PS-d8 film and a PS-d8 film where the SDS was washed away. There is less contrast between the surface and bulk in the SDS-treated sample, which could account for the elimination of the Tg confinement effect observed in films containing SDS [Chen and Torkelson, Polymer, 2016, 87, 226]. © The Royal Society of Chemistry 2018.
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    Evolution of the metallic state in LaNiO3/LaAlO3 superlattices measured by Li8β-detected NMR
    (American Physical Society (APS), 2021-11-12) Karner, VL; Chatzichristos, A; Cortie, DL; Fujimoto, D; Kiefl, RF; Levy, CDP; Li, RH; McFadden, RML; Morris, GD; Pearson, MR; Benckiser, E; Boris, AV; Cristiani, G; Logvenov, G; Keimer, B; MacFarlane, WA
    Using ion-implanted Li8 β-detected NMR, we study the evolution of the correlated metallic state of LaNiO3 in a series of LaNiO3/LaAlO3 superlattices as a function of bilayer thickness. Spin-lattice relaxation measurements in an applied field of 6.55T reveal two equal amplitude components: one with metallic (T linear) 1/T1 and a second with a more complex T dependence. The metallic character of the slow relaxing component is only weakly affected by the LaNiO3 thickness, while the fast component is much more sensitive, exhibiting the opposite temperature dependence (increasing toward low T) in the thinnest, most magnetic samples. The origin of this bipartite relaxation is discussed in terms of electronic phase separation. ©2021 American Physical Society.
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    Local electronic and magnetic properties of the doped topological insulators Bi2Se3:Ca and Bi2Te3 : Mn investigated using ion-implanted 8Li β-NMR
    (American Physical Society (APS), 2020-12-28) McFadden, RML; Chatzichristos, A; Cortie, DL; Fujimoto, D; San Hor, Y; Ji, H; Karner, VL; Kiefl, RF; Levy, CDP; Li, RH; McKenzie, I; Morris, GD; Pearson, MR; Stachura, M; Cava, RJ; MacFarlane, WA
    We report β-NMR measurements in Bi2Se3:Ca and Bi2Te3:Mn single crystals using Li+8 implanted to depths on the order of 100 nm. Above ∼200K, spin-lattice relaxation reveals diffusion of Li+8, with activation energies of ∼0.4eV (∼0.2eV) in Bi2Se3:Ca (Bi2Te3:Mn). At lower temperatures, the NMR properties are those of a heavily doped semiconductor in the metallic limit, with Korringa relaxation and a small, negative, temperature-dependent Knight shift in Bi2Se3:Ca. From this, we make a detailed comparison with the isostructural tetradymite Bi2Te2Se [McFadden, Phys. Rev. B 99, 125201 (2019)2469-995010.1103/PhysRevB.99.125201]. In the magnetic Bi2Te3:Mn, the effects of the dilute Mn moments predominate, but remarkably the Li+8 signal is not wiped out through the magnetic transition at 13 K, with a prominent critical peak in the spin-lattice relaxation that is suppressed in a high applied field. This detailed characterization of the Li+8 NMR response is an important step toward using depth-resolved β-NMR to study the low-energy properties of the chiral topological surface state in the Bi2Ch3 tetradymite topological insulator. ©2024 American Physical Society.
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    Local metallic and structural properties of the strongly correlated metal LaNiO3 using 8Li β–NMR
    (American Physical Society, 2019-10-07) Karner, VL; Chatzichristos, A; Cortie, DL; Dehn, MH; Foyevtsov, O; Foyevtsova, K; Fujimoto, D; Kiefl, RF; Levy, CDP; Li, R; McFadden, RML; Morris, GD; Pearson, MR; Stachura, M; Ticknor, JO; Cristiani, G; Logvenov, G; Wrobel, F; Keimer, B; Zhang, J; Mitchell, JF; MacFarlane, WA
    We report β-detected NMR of ion-implanted Li8 in a single crystal and thin film of the strongly correlated metal LaNiO3. Spin-lattice relaxation measurements reveal two distinct local environments, both metallic as evident from T-linear Korringa 1/T1 below 200K with slopes comparable to other metals. A small approximately temperature-independent Knight shift of ∼74ppm is observed, yielding a normalized Korringa product characteristic of substantial antiferromagnetic correlations. We find no evidence for a magnetic transition from 4 to 310K. The similarity of these features in the two very different samples indicates that they are intrinsic and unrelated to dilute oxygen vacancies. We attribute the two environments to two distinct but similar crystallographic Li8 sites and not to any form of phase inhomogeneity, but this is inconsistent with the conventional rhombohedral structure of LaNiO3, and also cannot be simply explained by the common alternative orthorhombic or monoclinic distortions. ©2024 American Physical Society.
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    The Site and High Field βNMR Properties of 8Li+ Implanted in α-Al2O3
    (IOP Publishing, 2023-03-01) MacFarlane, WA; Shenton, JK; Salman, Z; Chatzichristos, A; Cortie, DL; Dehn, M; Fujimoto, D; Karner, VL; Kiefl, RF; Koumoulis, D; Levy, CDP; McFadden, RML; McKenzie, I; Morris, GD; Pearson, MR; Stachura, M; Ticknor, JO
    We present high (> 2 T) magnetic field βNMR measurements of 8Li+ implanted in single crystals of sapphire, a commonly used backing material for other samples. From the well-resolved quadrupolar splitting, we extract the electric field gradient (EFG) at the implanted 8Li+ site. Comparison with supercell density functional theory calculations of the EFG allows us to identify the octahedral interstitial site as the most likely candidate. In contrast to the zero field βNQR spectra, where multiple singals are detected, only a single site is evident at high field. We discuss possible explanations for this discrepancy. The spin lattice relaxation is extremely slow (1/T1 < 0.02 s−1 ) over a broad temperature range from 4 to 300 K, demonstrating that cross relaxation with the 27Al nuclear spins is quenched in such high magnetic fields.