Browsing by Author "Chepurnov, VA"

Now showing 1 - 3 of 3
  • Thumbnail Image
    Item
    A luminescence study of porous diatoms
    (European Materials Research Society, 2004-05) Butcher, KSA; Ferris, JM; Phillips, MR; Wintrebert-Fouquet, M; Jong Wah, JW; Jovanovic, N; Vyverman, W; Chepurnov, VA
  • No Thumbnail Available
    Item
    Luminescence study of porous diatoms
    (Elsevier, 2005-12) Butcher, KSA; Ferris, JM; Phillips, MR; Wintrebert-Fouquet, M; Jong Wah, JW; Jovanovic, N; Vyverman, W; Chepurnov, VA
    The cathodoluminescent and photoluminescent properties of the nanoporous silica frustules of various diatom strains and of natural diatom samples are presented. The spectra are observed to be similar to that of pure silica glass and the phenology is therefore believed to also be somewhat similar. A strong U-V-blue luminescence peak is commonly observed as well as a yellow peak at 2.15 eV For the more heavily silicified field-collected freshwater benthic samples, a strong red peak at 1.95 eV is also observed. The 2.15 eV peak is also more strongly evident for the field-collected samples. The U-V-blue peak is related to common silica defect structure but cathodoluminescent microanalysis shows that this emission is highly localized in the diatom samples. © 2005, Elsevier Ltd.
  • No Thumbnail Available
    Item
    Small angle neutron scattering on an absolute intensity scale and the internal surface of diatom frustules from three species of differing morphologies
    (Springer, 2013-05-01) Garvey, CJ; Strobl, M; Percot, A; Šaroun, J; Haug, J; Vyverman, W; Chepurnov, VA; Ferris, JM
    The internal nanostructure of the diatoms Cyclotella meneghiniana, Seminavis robusta and Achnanthes subsessilis was investigated using small angle neutron scattering (SANS) to examine thin biosilica samples, consisting of isotropic (powder) from their isolated cell walls. The interpretation of SANS data was assisted by several other measurements. The N-2 adsorption, interpreted within the Branuer-Emmet-Teller isotherm, yielded the specific surface area of the material. Fourier transform infrared (FTIR) and Raman spectroscopy indicates that the isolated material is amorphous silica with small amounts of organic cell wall materials acting as a filling material between the silica particles. A two-phase (air and amorphous silica) model was used to interpret small angle neutron scattering data. After correction for instrumental resolution, the measurements on two SANS instruments covered an extended range of scattering vectors 0.0011 nm(-1) < q < 5.6 nm(-1), giving an almost continuous SANS curve over a range of scattering vectors, q, on an absolute scale of intensity for each sample. Each of the samples gave a characteristic scattering curve where log (intensity) versus log (q) has a -4 dependence, with other features superimposed. In the high-q regime, departure from this behaviour was observed at a length-scales equivalent to the proposed unitary silica particle. The limiting Porod scattering law was used to determine the specific area per unit of volume of each sample illuminated by the neutron beam. The Porod behaviour, and divergence from this behaviour, is discussed in terms of various structural features and the proposed mechanisms for the bio-assembly of unitary silica particles in frustules. © 2013, Springer.