Browsing by Author "Cadd, H"
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- ItemThe application of pollen radiocarbon dating and bayesian age-depth modeling for developing robust geochronological frameworks of wetland archives(Cambridge University Press for the Arizona Board of Regents on behalf of the University of Arizona, 2022-04-27) Cadd, H; Sherborne-Higgins, B; Becerra-Valdivia, L; Tibby, J; Barr, C; Forbes, MS; Cohen, TJ; Tyler, JJ; Vandergoes, MJ; Francke, A; Lewis, RJ; Jacobsen, GE; Marjo, CE; Turney, CSM; Arnold, LJWetland sediments are valuable archives of environmental change but can be challenging to date. Terrestrial macrofossils are often sparse, resulting in radiocarbon (14C) dating of less desirable organic fractions. An alternative approach for capturing changes in atmospheric 14C is the use of terrestrial microfossils. We 14C date pollen microfossils from two Australian wetland sediment sequences and compare these to ages from other sediment fractions (n = 56). For the Holocene Lake Werri Berri record, pollen 14C ages are consistent with 14C ages on bulk sediment and humic acids (n = 14), whilst Stable Polycyclic Aromatic Carbon (SPAC) 14C ages (n = 4) are significantly younger. For Welsby Lagoon, pollen concentrate 14C ages (n = 21) provide a stratigraphically coherent sequence back to 50 ka BP. 14C ages from humic acid and >100 µm fractions (n = 13) are inconsistent, and often substantially younger than pollen ages. Our comparison of Bayesian age-depth models, developed in Oxcal, Bacon and Undatable, highlight the strengths and weaknesses of the different programs for straightforward and more complex chrono-stratigraphic records. All models display broad similarities but differences in modeled age-uncertainty, particularly when age constraints are sparse. Intensive dating of wetland sequences improves the identification of outliers and generation of robust age models, regardless of program used. © The Author(s), 2022. Published by Cambridge University Press for the Arizona Board of Regents on behalf of the University of Arizona
- ItemComparing interglacials in eastern Australia: a multi-proxy investigation of a new sedimentary record(Elsevier, 2021-01-01) Forbes, MS; Cohen, TJ; Jacobs, Z; Marx, SK; Barber, E; Dodson, JR; Zamora, A; Cadd, H; Franke, A; Constantine, M; Mooney, SD; Short, J; Tibby, J; Parker, A; Cendón, DI; Peterson, MA; Tyler, JJ; Swallow, E; Haines, HA; Gadd, PS; Woodward, CAThe widespread formation of organic rich sediments in south-east Australia during the Holocene (Marine Isotope Stage [MIS] 1) reflects the return of wetter and warmer climates following the Last Glacial Maximum (LGM). Yet, little is known about whether a similar event occurred in the region during the previous interglacial (MIS 5e). A 6.8 m sediment core (#LC2) from the now ephemeral Lake Couridjah, Greater Blue Mountains World Heritage Area, Australia, provides insight into this question. Organic rich sediments associated with both MIS 1 and 5e are identified using 14C and optically stimulated luminescence (OSL) dating techniques. Also apparent are less organic sedimentary units representing MIS 6, 5d and 2 and a large depositional hiatus. Sediment δ13C values (−34 to −26‰) suggests that C3 vegetation dominates the organic matter source through the entire sequence. The pollen record highlights the prevalence of sclerophyll trees and shrubs, with local hydrological changes driving variations in the abundance of aquatic and lake-margin species. The upper Holocene sediment (0–1.7 m) is rich in organic matter, including high concentrations of total organic carbon (TOC; 20–40%), fine charcoal and macrophyte remains. These sediments are also characterised by a large proportion of epiphytic diatoms and a substantial biogenic component (chironomids and midges). These attributes, combined with low δ13C and δ15N values, and C:N ratios of approximately 20, indicate a stable peat system in a swamp like setting, under the modern/Holocene climate. In comparison, the lower organic rich unit (MIS 5e-d) has less TOC (5–10%), is relatively higher in δ13C and δ15N, and is devoid of macrophyte remains and biogenic material. Characterisation of the organic matter pool using 13C-NMR spectroscopy identified a strong decomposition signal in the MIS 5e organic sediments relative to MIS 1. Thus the observed shifts in δ13C, δ15N and C:N data between the two periods reflects changes in the organic matter pool, driven by decompositional processes, rather than environmental conditions. Despite this, high proportions of aquatic pollen taxa and planktonic diatoms in the MIS 5e–d deposits, and their absence in the Holocene indicates that last interglacial Lake Couridjah was deeper and, or, had more permanent water, than the current one. ©2020 Elsevier Ltd.
- ItemA detailed study of Holocene climate variability in south-east Australia based on cellulose inferred lake water isotopes and monitoring and modelling approach at Lake Surprise, western Victoria.(Australasian Quaternary Association Inc., 2022-12-06) Dharmarathma, A; Tyler, JJ; Tibby, J; Barr, C; Cadd, H; Ankor, MJ; Jones, MD; Tadros, CV; Hua, Q; Child, DP; Zawadzki, A; Hotchkis, MAC; Gadd, PS; Klaeb, RM; Hall, TDuring the Holocene, southeast Australia experienced intense climate conditions including extended droughts. However, knowledge of the frequency and intensity of such episodes is restricted due to the scarcity of quantitative, high-resolution climate records from the region. Where conditions are possible, oxygen isotopes preserved in lake sediments are a useful tool for retracing the past climatic and environment. Here we present a well-dated, highly resolved Holocene record based on δ18O values of aquatic cellulose, alongside organic carbon isotopes and carbon/nitrogen ratios from sediments at Lake Surprise in western Victoria. Our interpretation of the palaeo-data is supported by both monitoring of water and sediment accumulation and lake isotope mass balance modelling to track the modern hydrology of the lake. The lake is highly groundwater dependant alongside its evaporative enrichment of major ions and stable isotopes. The cellulose record indicates a trend of gradually increasing aridity towards the present day, with notable extreme wet periods prevailing from 10900 – 10000, 7600 – 7000 and 5600 – 4500 cal yr BP. the lake represent a significant climate transition to towards aridity at 4500 cal yr BP and remained consistent over the last 4000 years, along with the driest period recorded from 2000 – 1550 cal yr BP. while our record is consistent with other studies from western Victoria, we demonstrate a strong coherence with SWW variability suggesting that the southern Ocean processes were the dominant controls of Holocene climate change at least over the study area. Further, we suggest an increasing influence of ENSO and IOD during the last two millennia. Our record also agrees with the pattern of variation in solar forcing to some extent which may symbolize a connection to proxy data and climate drivers. However, detailed analyses focused on solar activity and climate modes are required to understand teleconnections among these climate drivers and their mechanisms.
- ItemDifferentiating between the d13C signature from environmental conditions and SOM cycling in eastern Australian peat sediments(Australasian Quaternary Association (AQUA), 2021-07-08) Forbes, MS; Cohen, TJ; Marx, SK; Sherborne-Higgins, B; Cadd, H; Francke, A; Cendón, DI; Peterson, MA; Mooney, SD; Constantine, M; Boesl, F; Kobayashi, Y; Mazumder, DThe analysis of stable carbon isotopes is commonly used in Quaternary science to reconstruct the environmental conditions and vegetation contributions to sedimentary sequences. However, the measured d13C signature of the total organic matter (OM) pool can also reflect other complexities within depositional environments. The peats of the Thirlmere Lakes system in the southern section of the Blue Mountains World Heritage Area provides an excellent opportunity to closely scrutinise such d13C dynamics. These deposits are rich in TOC (20-40%) meaning analytical techniques such as 13C-NMR, used to characterise the OM pool, can be applied effectively. Furthermore, the identification of several peat units deposited over the last ~130 ka allows for temporal comparisons. d13C values determined for a 7 m sediment sequence from Lake Couridjah representing both the MIS 1 and MIS 5e interglacial periods vary by up to 4 to 6‰. These trends were subsequently identified in two other sediment sequences (Lake Baraba and Lake Werri Berri) proximal to Lake Couridjah. Initially we interpreted our results as reflecting a C3 dominated vegetation environment with MIS 1 wetter than MIS 5e, following the established relationship between water stress and d13C enrichment. However, spectral analysis of the OM pool indicates that d13C is driven by changing OM dynamics rather than large changes in environmental conditions. In these environments, the greater presence of carbohydrates (i.e. cellulose) in MIS 1 result in more depleted d13C values. In contrast, the MIS 5e peat is dominated by relative inert OM C fractions including charcoal and lipids (such as leaf waxes), which influences environmental proxies such as C/N. Thus, it is likely that the older MIS 5e peat is a more decomposed version of the active MIS 1 peat, and thus differentiating environmental conditions between the two using d13C alone is not particularly illuminating. To overcome this, we describe the d13C values for a coarse charcoal and high temperature hydrogen pyrolysis fractions, modern vegetation, catchment POC and DOC, and n-alkanes composition and generate catchment carbon models for both MIS 1 and MIS5e. Finally comparing the size of the OM pools of both interglacial deposits can provide useful information in estimating the carbon storage capacity of peat deposits in eastern Australia over these time scales. © The Authors.
- ItemDifferentiating between the d13C signature from environmental conditions and SOM cycling in eastern Australian peat sediments(Australasian Environmental Isotope Conference, 2022-11-14) Forbes, MS; Cohen, TJ; Marx, SK; Sherborne-Higgins, B; Cadd, H; Francke, A; Cendón, DI; Peterson, MA; Mooney, SD; Constantine, M; Boesl, F; Kobayashi, Y; Mazumder, DThe analysis of stable carbon isotopes is commonly used in Quaternary science to reconstruct the environmental conditions and vegetation contributions to sedimentary sequences. However, the measured d13C signature of the total organic matter (OM) pool can also reflect other complexities within depositional environments. The peats of the Thirlmere Lakes system in the southern section of the Blue Mountains World Heritage Area provides an excellent opportunity to closely scrutinise such d13C dynamics. These deposits are rich in TOC (20-40%) meaning analytical techniques such as 13C-NMR, used to characterise the OM pool, can be applied effectively. Furthermore, the identification of several peat units deposited over the last ~130 ka allows for temporal comparisons. d13C values determined for a 7 m sediment sequence from Lake Couridjah representing both the MIS 1 and MIS 5e interglacial periods vary by up to 4 to 6‰. These trends were subsequently identified in two other sediment sequences (Lake Baraba and Lake Werri Berri) proximal to Lake Couridjah. Initially we interpreted our results as reflecting a C3 dominated vegetation environment with MIS 1 wetter than MIS 5e, following the established relationship between water stress and d13C enrichment. However, spectral analysis of the OM pool indicates that d13C is driven by changing OM dynamics rather than large changes in environmental conditions. In these environments, the greater presence of carbohydrates (i.e. cellulose) in MIS 1 result in more depleted d13C values. In contrast, the MIS 5e peat is dominated by relative inert OM C fractions including charcoal and lipids (such as leaf waxes), which influences environmental proxies such as C/N. Thus, it is likely that the older MIS 5e peat is a more decomposed version of the active MIS 1 peat, and thus differentiating environmental conditions between the two using d13C alone is not particularly illuminating. To overcome this, we describe the d13C values for a coarse charcoal and high temperature hydrogen pyrolysis fractions, modern vegetation, catchment POC and DOC, and n-alkanes composition and generate catchment carbon models for both MIS 1 and MIS5e. Finally comparing the size of the OM pools of both interglacial deposits can provide useful information in estimating the carbon storage capacity of peat deposits in eastern Australia over these time scales.
- ItemHolocene climate variability in south east Australia; inferred from oxygen isotopes in sedimentary cellulose at Lake Surprise, Victoria(European General Assembly, 2022-05-23) Dharmarathna, A; Tyler, JJ; Barr, C; Tibby, J; Jones, MD; Anjor, MJ; Cadd, H; Gadd, PS; Hua, Q; Child, DP; Zawadski, A; Hotchkis, MAC; Zolitschka, BSouth east Australia experienced periods of multi-year droughts particularly within the last 2 millennia. However, given the limited evidence from smaller number of sites and scarcity of quantitative, high-resolution climate records, it is largely unknown whether these droughts are a feature of climate through the Holocene and the extent to which they are experienced throughout the region. Where conditions are suitable, oxygen isotopes preserved in lake sediments are a useful tool for reconstructing past climate and environmental conditions. Here, we present preliminary results of a Holocene length record from Lake Surprise in western Victoria, from which we analysed δ18O of aquatic cellulose as a proxy for lake-water δ18O, complemented by organic carbon/nitrogen ratios, organic carbon isotopes and XRF (ITRAX) inferred elemental composition. Our interpretation of the palaeo-data is supported by ~3 monthly monitoring of water and sediment geochemistry to track the modern hydrology of the lake. Our preliminary results show a strong positive correlation between precipitation and sedimentary calcium (carbonate deposition) over the last 150 years, likely linked to changes in primary productivity. The aquatic cellulose δ18O record through Holocene is also correlated with carbonate concentration, reinforcing our interpretation of CaCO3 deposition in the lake during wet periods. The cellulose δ18O record indicates a trend of gradually increasing aridity from early to late Holocene, with a notable extremely dry phase over the last 2 ka. Comparison of the cellulose δ18O record with high-resolution Holocene climate records indicates that multiple climate drivers such as ENSO intensification and Antarctic warming are strongly linked to increasing aridity of the region. Further work will focus on both increasing the resolution of the record to better identify the frequency and duration of key events and on quantifying natural hydroclimate variability, particularly via lake hydrologic modelling to better constrain the paleoclimate record. © Author(s) 2022. Creative Commons Attribution 4.0 Licence.
- ItemHolocene climate variability in south-eastern Australia; inferred from oxygen isotopes in sedimentary cellulose at Lake Surprise, Victoria(Australasian Quaternary Association (AQUA), 2021-07-08) Dharmarathna, A; Tyler, JJ; Barr, C; Tibby, J; Jones, MD; Ankor, MJ; Gadd, PS; Hua, Q; Child, DP; Zawadzki, A; Hotchkis, MAC; Zolitschka, B; Cadd, HDuring the Holocene, south-eastern Australia experienced periods of multi-year drought. However, the scarcity of quantitative, high-resolution climate records from the region means understanding of the frequency and intensity of such events is limited. Where conditions are suitable, oxygen isotopes preserved in lake sediments are a useful tool for reconstructing past climate and environmental conditions. Here, we present preliminary results from a ca. 8700 ka record from Lake Surprise in western Victoria, from which we analysed δ18O of aquatic cellulose, alongside organic carbon/nitrogen ratios, organic carbon isotopes and XRF (ITRAX) inferred elemental composition. Our interpretation of the palaeo- data is supported by ~3 monthly monitoring of water and sediment geochemistry to track the modern hydrology of the lake. Our preliminary results show a strong positive correlation between meteorological precipitation data and sedimentary calcium (carbonate deposition) over the last 150 years, likely linked to changes in primary productivity. As a proxy for lake-water δ18O, the aquatic cellulose δ18O record is also correlated with carbonate concentration, reinforcing our interpretation of CaCO3 deposition in the lake during wet periods. The cellulose δ18O record indicates a trend of gradually increasing aridity over the last 8 ka, with a notable extremely wet period ca. 7.5–7 ka and a dry period ca 2–1.5 ka. Further work will focus on increasing the resolution of the data to better identify the frequency and duration of key events and quantifying natural hydroclimatic variability, alongside continued geochemical monitoring and modelling to better constrain the interpretation of the palaeoclimate record.
- ItemHolocene climate, fire and ecosystem change on Kangaroo Island, South Australia(Australian Nuclear Science and Technology Organisation, 2021-11-17) Duxbury, LC; Tyler, JJ; Armbrecht, L; Francke, A; Cadd, H; Law, WB; Zawadzki, A; Child, DP; Gadd, PS; Jacobsen, GE; Tibby, J; Mitchell, KIntroduction Fire has long been a familiar and important part of Australian landscapes. However, anthropogenic climate change has heralded major shifts in fire regimes, negatively impacting ecosystems. These effects are expected to worsen in coming years, but there remain difficulties with projecting fire regime trajectories and their environmental impacts, in part due to a lack of data on centennial to millennial timescales. Uncertainties remain concerning the independent effects of climate and human impact on bushfires, and the long term impacts of fire on both terrestrial and aquatic ecosystems. Aims This study aims to address these uncertainties by returning to Lashmars Lagoon, Kangaroo Island, a site of pioneering palaeoenvironmental research in South Australia that has been overlooked in recent decades. Kangaroo Island presents a fascinating case study, due to the putative abandonment of the island by ancient Aboriginal populations ~ 2,500 years ago. As such, it represents a unique opportunity to study the impact of cessation of Aboriginal management practices on ecosystems prior to European invasion. Methods We collected a ~ 7.5 metre long sediment core from Lashmars Lagoon, which we expected, from the work of previous studies, to span the past 5,000 years. We are combining multiple traditional and novel palaeoecological and geochemical proxies to infer both fire, catchment and ecosystem variability, augmented by an age model based on Pb-210, Pu isotopic profiling and C-14 dating. Results Our preliminary age model determined our core to span the past ~ 7,000 years, an adjustment to previous estimates. Our model is based on the radiocarbon dating of 6 plant macrofossils, 2 pollen samples and 1 shell. The pollen dates concur well with the plant macrofossils. The shell demonstrates an older age than the other samples from a similar horizon, a 'reservoir effect' that is expected from the integration of older carbon into the sample. The model also integrates 15 Pb-210 dates from the uppermost 30 cm, verified by the establishment of a nuclear bomb testing peak from Pu isotopic profiling. The broad peak detected in the Pu profile is also worthwhile of mention. Further interrogation of this phenomenon could be useful to infer certain processes the uppermost sediments, such as bioturbation, lateral leaching of Pu in the sediment or disturbance from the coring process. Overall, the age model indicates a constant rate of sedimentation approximately 1 mm/yr across the entire length of the, a somewhat surprising result given the considerable variation in sedimentology. Conclusions The development of a robust age model is integral to the interpretation of environmental, geochemical and climatic proxies at Lashmars Lagoon, South Australia. Importantly, the better constraint of our age model improves certainty around the timing of the human exodus from Kangaroo Island and the resultant discontinuation of Indigenous fire management. © The Authors
- ItemThe influence of fine-scale topography on the impacts of Holocene fire in a Tasmanian montane landscape(John Wiley & Sons, Inc, 2019-07-23) Cadd, H; Fletcher, MS; Mariani, M; Heijnis, H; Gadd, PSTasmania's montane temperate rainforests contain some of Australia's most ancient and endemic flora. Recent landscape-scale fires have impacted a significant portion of these rainforest ecosystems. The complex and rugged topography of Tasmania results in a highly variable influence of fire across the landscape, rendering predictions of ecosystem response to fire difficult. We assess the role of topographic variation in buffering the influence of fire in these endemic rainforest communities. We developed a new 14 000-year (14-ka) palaeoecological dataset from Lake Perry, southern Tasmania, and compared it to neighbouring Lake Osborne (<250 m distant) to examine how topographic variations influence fire and vegetation dynamics through time. Repeated fire events during the Holocene cause a decline in montane rainforest taxa at both sites; however, in the absence of fire, rainforest taxa are able to recover. Montane temperate rainforest taxa persisted at Lake Perry until European settlement, whilst these taxa were driven locally extinct and replaced by Eucalyptus species at Lake Osborne after 2.5 ka. Contiguous topographic fire refugia within the Lake Perry catchment probably provided areas of favourable microclimates that discouraged fire spread and supported the recovery of these montane temperate rainforests. Copyright © 2019 John Wiley & Sons, Ltd.
- ItemThe new Chronos 14carbon-Cycle Facility, University of New South Wales, Sydney, Australia.(Australian Nuclear Science and Technology Organisation, 2021-11-17) Turney, CSM; Thomas, Z; Becerra-Valdivia, L; Palmer, JG; Haines, HA; Cadd, H; Wacker, L; Baker, AA; Andersen, MS; Jacobsen, GE; Meredith, KT; Chinu, K; Hiscock, W; Vohra, J; Marjo, CEThe Chronos 14Carbon-Cycle Facility is a new radiocarbon laboratory at the University of New South Wales, Australia. Built around an Ionplus 200 kV MIni-CArbon DAting System (MICADAS) Accelerator Mass Spectrometer (AMS) installed in October 2019, the facility was established to address major challenges in the Earth, Environmental and Archaeological sciences. Here we report an overview of the Chronos facility, the pretreatment methods currently employed (bones, carbonates, peat, pollen, charcoal, and wood) and results of radiocarbon and stable isotope measurements undertaken on a wide range of sample types. Our measurements on international standards, known-age and blank samples demonstrate that the facility is capable of measuring 14C samples from the Anthropocene back to nearly 50,000 years ago. Future work will focus on improving our understanding of the Earth system and managing resources in a future warmer world.
- ItemRadiocarbon protocols and first intercomparison results from the Chronos 14Carbon-Cycle Facility, University of New South Wales, Sydney, Australia(Cambridge University Press, 2021-05-11) Turney, CSM; Becerra-Valdivia, L; Sookdeo, A; Thomas, ZA; Palmer, JG; Haines, HA; Cadd, H; Wacker, L; Baker, AA; Andersen, MS; Jacobsen, GE; Meredith, KT; Chinu, K; Bollhalder, S; Marjo, CEThe Chronos 14Carbon-Cycle Facility is a new radiocarbon laboratory at the University of New South Wales, Australia. Built around an Ionplus 200 kV MIni-CArbon DAting System (MICADAS) Accelerator Mass Spectrometer (AMS) installed in October 2019, the facility was established to address major challenges in the Earth, Environmental and Archaeological sciences. Here we report an overview of the Chronos facility, the pretreatment methods currently employed (bones, carbonates, peat, pollen, charcoal, and wood) and results of radiocarbon and stable isotope measurements undertaken on a wide range of sample types. Measurements on international standards, known-age and blank samples demonstrate the facility is capable of measuring 14C samples from the Anthropocene back to nearly 50,000 years ago. Future work will focus on improving our understanding of the Earth system and managing resources in a future warmer world. © The Author(s) 2021. Published by Cambridge University Press for the Arizona Board of Regents on behalf of the University of Arizona.