Browsing by Author "Artiaga, D"

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    The elemental sulfur ore deposit of Salmerón: Las Minas de Hellín basin (Late Miocene, SE Spain)
    (Instituto Geologico y Minero de Espana, 2022-06) García-Veigas, J; Gimeno, D; Pineda, V; Cendón, DI; Sánchez-Román, M; Artiaga, D; Bembibre, G
    Strata-bound elemental sulfur deposits occur in different circum-Mediterranean Miocene sedimentary successions containing evaporites and high amounts of organic matter. It is widely known that bacterial sulfate reduction processes are the triggering mechanisms involved in the origin of hydrogen sulfide and the subsequent native sulfur. However, in most of these sedimentary successions, there is controversy over whether elemental sulfur formed in the basin floor, as the same time as the sediments (biosyngenetic), or later, during diagenesis (bioepigenetic). Las Minas de Hellín basin, in the SE Spain, contains one of the largest elemental sulfur deposits in Europe. Based on data recovered from mining company (1903 -1960) and a borehole campaign performed by MINERSA between 1987 and 1988, two native sulfur ore bodies are recognized. The upper sulfur body is hosted by carbonates and diatom-rich levels, whereas the lower sulfur body, only exploited in underground mines now closed, is hosted by gypsum. This work shows a petrological and geochemical study of core samples from the upper sulfur body in the Salmerón area (Murcia), 500 m west of the widely exploited area of Las Minas de Hellín (Albacete). In Salmerón, elemental sulfur occurs as pseudomorphs after primary sedimentary gypsum as well as filling fractures and bed joints. The elemental sulfur replacement is also related to calcification and silicification of the sedimentary biomediated dolomite. The mineralization is considered bioepigenetic formed during early diagenesis. Contribution from hydrothermal waters circulating through adjacent faults are not ruled out. ©2022 CSIC. This is an open-access article distributed under the terms of the Creative Commons Attribution 4.0 International (CC BY 4.0) License
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    Geochemical indicators in Western Mediterranean Messinian evaporites: implications for the salinity crisis
    (Elsevier B. V., 2018-09-01) García-Veigas, J; Cendón, DI; Gilbert, L; Lowenstein, TK; Artiaga, D
    The Messinian Salinity Crisis (MSC) led to deposition of one of the youngest saline giant on Earth. The increasing restriction of the connections between the Mediterranean, the Atlantic Ocean and the freshwater Paratethyan basins resulted in the deposition of massive amounts of evaporites (gypsum, anhydrite, halite and potash salts) in shallow marginal basins as well as in deep Mediterranean basins. Here we show that each gypsum unit in the circum-Mediterranean marginal basins in Sicily and Spain is characterized by a narrow range of sulfate isotopic values (δ34S ~ 23‰ and δ18O ~ 14‰ in the Lower Gypsum; δ34S ~ 23‰ and δ18O ~ 17‰ in the Upper Gypsum). Sulfate isotope compositions found in MSC evaporites from a variety of circum-Mediterranean basins are homogenously high relative to expected Late Miocene marine evaporites (δ34S ~ 22‰ and δ18O ~ 12‰). This points to a stratified Mediterranean Sea with a high-salinity, dense, and anoxic bottom water mass. An intermediate depth gypsum-saturated brine flooded marginal basins from which selenite deposits formed during the MSC Stage 1 (Primary Lower Gypsum) and MSC Stage 3 (Upper Gypsum). Messinian brines were gradually affected by biogenic redox processes and isotopically differentiated from global seawater values. The homogeneity of isotopic signatures between distant synchronous gypsum deposits further supports the deep-basin deep-water model for the Mediterranean during the entire MSC event. © 2018 Elsevier B.V.
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    Late Miocene evaporite geochemistry of lorca and fortuna basins (Eastern Betics, SE Spain): evidence of restriction and continentalization
    (Wiley, 2020-09-26) García‐Veigas, J; Gibert, L; Cendón, DI; Artiaga, D; Corbí, H; Soria, JM; Lowenstein, TK; Sanz, E
    The Lorca and Fortuna basins are two intramontane Neogene basins located in the eastern Betic Cordillera (SE Spain). During the Late Tortonian—Early Messinian, marine and continental evaporites precipitated in these basins as a consequence of increased marine restriction and isolation. Here we show a stratigraphic correlation between the evaporite records of these basins based on geochemical indicators. We use SO4 isotope compositions and Sr isotopic ratios in gypsum, and halite Br contents to characterize these units and to identify the marine or continental source of the waters feeding the evaporite basins. In addition, we review the available chronological information used to date these evaporites in Lorca (La Serrata Fm), including a thick saline deposit, that we correlate with the First Evaporitic Group in Fortuna (Los Baños Fm). This correlation is also supported by micropalaeontological data, giving a Late Tortonian age for this sequence. The Second Evaporitic Group, (Chicamo Fm), and the Third Evaporitic Group (Rambla Salada Fm) developed only in Fortuna during the Messinian. According to the palaeogeographical scheme presented here, the evaporites of the Lorca and Fortuna basins were formed during the Late Tortonian—Early Messinian, close to the Betic Seaway closure. Sulphate isotope compositions and Sr isotopic ratios of the Ribera Gypsum Mb, at the base of the Rambla Salada Fm (Fortuna basin), match those of the Late Messinian selenite gypsum beds in San Miguel de Salinas, in the near Bajo Segura basin (40 km to the East), and other Messinian Salinity Crisis gypsum deposits in the Mediterranean. According to these geochemical indicators and the uncertainty of the chronology of this unit, the assignment of the Rambla Salada Fm to the MSC cannot be ruled out. © 1999-2024 John Wiley & Sons, Inc or related companies.
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    Late Miocene evaporite geochemistry of Lorca and Fortuna basins (Eastern Betics, SE Spain): Evidence of restriction and continentalization
    (John Wiley & Sons, Inc., 2019-09-26) García-Veigas, J; Gilbert, L; Cendón, DI; Artiaga, D; Corbí, H; Soria, JM; Lowenstein, TK; Sanz, E
    The Lorca and Fortuna basins are two intramontane Neogene basins located in the eastern Betic Cordillera (SE Spain). During the Late Tortonian—Early Messinian, marine and continental evaporites precipitated in these basins as a consequence of increased marine restriction and isolation. Here we show a stratigraphic correlation between the evaporite records of these basins based on geochemical indicators. We use SO4 isotope compositions and Sr isotopic ratios in gypsum, and halite Br contents to characterize these units and to identify the marine or continental source of the waters feeding the evaporite basins. In addition, we review the available chronological information used to date these evaporites in Lorca (La Serrata Fm), including a thick saline deposit, that we correlate with the First Evaporitic Group in Fortuna (Los Baños Fm). This correlation is also supported by micropalaeontological data, giving a Late Tortonian age for this sequence. The Second Evaporitic Group, (Chicamo Fm), and the Third Evaporitic Group (Rambla Salada Fm) developed only in Fortuna during the Messinian. According to the palaeogeographical scheme presented here, the evaporites of the Lorca and Fortuna basins were formed during the Late Tortonian—Early Messinian, close to the Betic Seaway closure. Sulphate isotope compositions and Sr isotopic ratios of the Ribera Gypsum Mb, at the base of the Rambla Salada Fm (Fortuna basin), match those of the Late Messinian selenite gypsum beds in San Miguel de Salinas, in the near Bajo Segura basin (40 km to the East), and other Messinian Salinity Crisis gypsum deposits in the Mediterranean. According to these geochemical indicators and the uncertainty of the chronology of this unit, the assignment of the Rambla Salada Fm to the MSC cannot be ruled out. © 2019 The Authors. Basin Research © 2019 John Wiley & Sons Ltd, European Association of Geoscientists & Engineers and International Association of Sedimentologists
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    The Messinian evaporites of the Mesaoria basin (North Cyprus): a discrepancy with the current chronostratigraphic understanding
    (Elsevier B. V., 2021-10-04) Artiaga, D; García-Veigas, J; Cendón, DI; Atalar, C; Gilbert, L
    Large volume of evaporites were deposited during the Messinian Salinity Crisis (MSC) across the Mediterranean. These evaporites are currently outcropping on land and are interpreted by seismic profiles beneath the Mediterranean floor. Biostratigraphic, magnetostratigraphic and astrochronologic data recovered from sediments below and above outcropping evaporites, together with gypsum facies associations and stratigraphic cyclicity, are the cornerstone of what is known as the MSC ‘three-stage’ model: Primary Lower Gypsum (PLG) – MSC stage 1, Resedimented Lower Gypsum (RLG) - MSC stage 2, and Upper Gypsum (UG) – MSC stage 3. Although this litho- and chronostratigraphic model is mainly based on the gypsum succession in Sicily, it is being currently applied by many investigators across the Mediterranean. The Mesaoria basin, in North Cyprus, hosts well exposed MSC gypsum deposits of the Kalavasos Fm. Two informal units are distinguished in the gypsum succession. The lower unit, largely consisting of clastic gypsum deposits, is conformably overlaid by the upper unit, mostly consisting of ‘in situ’ vertically-oriented selenite deposits. Based on the lithostratigraphic gypsum succession, the lower unit could be tentatively assigned to RLG - MSC stage 2, while the upper unit could correspond to UG - MSC stage 3. However, our lithologic and geochemical (δ34Ssulfate δ18Osulfate, 87Sr/86Sr) data in gypsum points that the upper unit fits with those of the PLG – MSC stage 1. For the first time, thick vertically-oriented selenite beds with lithofacies and geochemical signatures diagnostic of PLG deposits lay conformably over clastic gypsum successions diagnostic of RLG deposits in the currently accepted ‘three-stage’ model. In North Cyprus, ‘in situ’ selenite platforms and ‘clastic’ gravity-flow gypsum deposits are coeval involving erosion and redeposition during the same evolutive stage. The complete gypsum succession in North Cyprus must be considered as MSC Lower Evaporites in the ‘two-step’ model (Lower Evaporites and Upper Evaporites) classically proposed prior to the ‘three-stage’ model. We show how nearby Messinian evaporite basins in the same island (North and South Cyprus) can produce different sedimentary records. Our data cast doubts on the systematic application of the ‘three-stage’ litho- and chronostratigraphic model to North Cyprus and other MSC Mediterranean evaporite successions. This work highlights the importance of local processes in the sedimentation and distribution of MSC evaporites in active tectonic settings, and alerts against extrabasinal MSC correlations based on gypsum facies distribution. © The Authors CC BY 4.0