Host–guest adsorption behavior of deuterated methane and molecular oxygen in a porous rare-earth metal–organic framework

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dc.contributor.authorOgilvie, SHen_AU
dc.contributor.authorDuyker, SGen_AU
dc.contributor.authorSouthon, PDen_AU
dc.contributor.authorPeterson, VKen_AU
dc.contributor.authorKepert, CJen_AU
dc.date.accessioned2016-10-10T23:32:22Zen_AU
dc.date.available2016-10-10T23:32:22Zen_AU
dc.date.issued2014-11-17en_AU
dc.date.statistics2016-10-11en_AU
dc.description.abstractThe yttrium-based metal–organic framework, Y(btc) (btc = 1,3,5-benzenetricarboxylate), shows moderate uptake of methane (0.623 mmol g−1) and molecular oxygen (0.183 mmol g−1) at 1 bar and 308 K. Neutron powder-diffraction data for the guest-free, CD4-, and O2-loaded framework reveal multiple adsorption sites for each gas. Both molecular guests exhibit interactions with the host framework characterised by distances between the framework and guest atoms that range from 2.83 to 4.81 Å, with these distances identifying interaction most commonly between the guest molecule and the carboxylate functional groups of the benzenetricarboxylate bridging ligand of the host. © 2014, International Centre for Diffraction Data.en_AU
dc.identifier.citationOgilvie, S. H., Duyker, S. G., Southon, P. D., Peterson, V. K., & Kepert, C. J. (2014). Host–guest adsorption behavior of deuterated methane and molecular oxygen in a porous rare-earth metal–organic framework. Proceedings of the Australian X-Ray Analytical Association (AXAA) Conference held February 9-13, 2014, Pan Pacific Hotel, Perth, WA. In Powder Diffraction, 29(SupplementS1), S96-S101. doi:10.1017/S0885715614001158en_AU
dc.identifier.conferenceenddate13 February 2014en_AU
dc.identifier.conferencenameAustralian X-Ray Analytical Association (AXAA) Conferenceen_AU
dc.identifier.conferenceplacePerth, Western Australiaen_AU
dc.identifier.conferencestartdate9 February 2014en_AU
dc.identifier.govdoc7260en_AU
dc.identifier.issueSupplement 1en_AU
dc.identifier.journaltitlePowder Diffractionen_AU
dc.identifier.paginationS96-S101en_AU
dc.identifier.urihttp://dx.doi.org/10.1017/S0885715614001158en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/7698en_AU
dc.identifier.volume29en_AU
dc.language.isoenen_AU
dc.publisherCambridge Coreen_AU
dc.subjectMetalsen_AU
dc.subjectMethaneen_AU
dc.subjectMolecular structureen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectOxygenen_AU
dc.subjectLigandsen_AU
dc.titleHost–guest adsorption behavior of deuterated methane and molecular oxygen in a porous rare-earth metal–organic frameworken_AU
dc.typeConference Paperen_AU
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